Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as i...
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Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2021
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oai:doaj.org-article:442fc4f1b40446f0ba6c7921307dc7572021-12-01T05:53:11ZSynthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy2411-141410.15826/chimtech.2021.8.3.05https://doaj.org/article/442fc4f1b40446f0ba6c7921307dc7572021-09-01T00:00:00Zhttps://journals.urfu.ru/index.php/chimtech/article/view/5186https://doaj.org/toc/2411-1414Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as isocyanates. In this case, freshly distilled toluene was used as a solvent. The structures of the obtained compounds were confirmed by the data of IR and NMR1H spectroscopy. Using the synthesized compounds, formulations of compositions for electrodeposition of a tin-indium alloy on a copper wire were developed. The possibility of using silylureas of various structures as effective surfactants used in the electrodeposition of the tin-indium alloy is shown. The operational characteristics of the obtained wire were investigated, including the wire diameter, coating thickness, tensile strength, electrical resistance, and direct current electrical resistivity.K. Yu. IvanovaM. V. KuzminL. G. RogozhinaA. O. PatianovaV. L. SemenovR. I. AlexandrovUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina articleisophorone diisocyanatehexamethylene diisocyanate2,4-toluene diisocyanate3-aminopropyltriethoxysilanepolyfunctional silylureaselectrodepositionindium-tin alloycopper wireelectrodesolar panelsChemistryQD1-999ENRUChimica Techno Acta, Vol 8, Iss 3 (2021) |
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DOAJ |
language |
EN RU |
topic |
isophorone diisocyanate hexamethylene diisocyanate 2,4-toluene diisocyanate 3-aminopropyltriethoxysilane polyfunctional silylureas electrodeposition indium-tin alloy copper wire electrode solar panels Chemistry QD1-999 |
spellingShingle |
isophorone diisocyanate hexamethylene diisocyanate 2,4-toluene diisocyanate 3-aminopropyltriethoxysilane polyfunctional silylureas electrodeposition indium-tin alloy copper wire electrode solar panels Chemistry QD1-999 K. Yu. Ivanova M. V. Kuzmin L. G. Rogozhina A. O. Patianova V. L. Semenov R. I. Alexandrov Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
description |
Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as isocyanates. In this case, freshly distilled toluene was used as a solvent. The structures of the obtained compounds were confirmed by the data of IR and NMR1H spectroscopy. Using the synthesized compounds, formulations of compositions for electrodeposition of a tin-indium alloy on a copper wire were developed. The possibility of using silylureas of various structures as effective surfactants used in the electrodeposition of the tin-indium alloy is shown. The operational characteristics of the obtained wire were investigated, including the wire diameter, coating thickness, tensile strength, electrical resistance, and direct current electrical resistivity. |
format |
article |
author |
K. Yu. Ivanova M. V. Kuzmin L. G. Rogozhina A. O. Patianova V. L. Semenov R. I. Alexandrov |
author_facet |
K. Yu. Ivanova M. V. Kuzmin L. G. Rogozhina A. O. Patianova V. L. Semenov R. I. Alexandrov |
author_sort |
K. Yu. Ivanova |
title |
Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
title_short |
Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
title_full |
Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
title_fullStr |
Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
title_full_unstemmed |
Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
title_sort |
synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy |
publisher |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
publishDate |
2021 |
url |
https://doaj.org/article/442fc4f1b40446f0ba6c7921307dc757 |
work_keys_str_mv |
AT kyuivanova synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy AT mvkuzmin synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy AT lgrogozhina synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy AT aopatianova synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy AT vlsemenov synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy AT rialexandrov synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy |
_version_ |
1718405470805295104 |