Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy

Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as i...

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Autores principales: K. Yu. Ivanova, M. V. Kuzmin, L. G. Rogozhina, A. O. Patianova, V. L. Semenov, R. I. Alexandrov
Formato: article
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RU
Publicado: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2021
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Acceso en línea:https://doaj.org/article/442fc4f1b40446f0ba6c7921307dc757
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spelling oai:doaj.org-article:442fc4f1b40446f0ba6c7921307dc7572021-12-01T05:53:11ZSynthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy2411-141410.15826/chimtech.2021.8.3.05https://doaj.org/article/442fc4f1b40446f0ba6c7921307dc7572021-09-01T00:00:00Zhttps://journals.urfu.ru/index.php/chimtech/article/view/5186https://doaj.org/toc/2411-1414Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as isocyanates. In this case, freshly distilled toluene was used as a solvent. The structures of the obtained compounds were confirmed by the data of IR and NMR1H spectroscopy. Using the synthesized compounds, formulations of compositions for electrodeposition of a tin-indium alloy on a copper wire were developed. The possibility of using silylureas of various structures as effective surfactants used in the electrodeposition of the tin-indium alloy is shown. The operational characteristics of the obtained wire were investigated, including the wire diameter, coating thickness, tensile strength, electrical resistance, and direct current electrical resistivity.K. Yu. IvanovaM. V. KuzminL. G. RogozhinaA. O. PatianovaV. L. SemenovR. I. AlexandrovUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina articleisophorone diisocyanatehexamethylene diisocyanate2,4-toluene diisocyanate3-aminopropyltriethoxysilanepolyfunctional silylureaselectrodepositionindium-tin alloycopper wireelectrodesolar panelsChemistryQD1-999ENRUChimica Techno Acta, Vol 8, Iss 3 (2021)
institution DOAJ
collection DOAJ
language EN
RU
topic isophorone diisocyanate
hexamethylene diisocyanate
2,4-toluene diisocyanate
3-aminopropyltriethoxysilane
polyfunctional silylureas
electrodeposition
indium-tin alloy
copper wire
electrode
solar panels
Chemistry
QD1-999
spellingShingle isophorone diisocyanate
hexamethylene diisocyanate
2,4-toluene diisocyanate
3-aminopropyltriethoxysilane
polyfunctional silylureas
electrodeposition
indium-tin alloy
copper wire
electrode
solar panels
Chemistry
QD1-999
K. Yu. Ivanova
M. V. Kuzmin
L. G. Rogozhina
A. O. Patianova
V. L. Semenov
R. I. Alexandrov
Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
description Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as isocyanates. In this case, freshly distilled toluene was used as a solvent. The structures of the obtained compounds were confirmed by the data of IR and NMR1H spectroscopy. Using the synthesized compounds, formulations of compositions for electrodeposition of a tin-indium alloy on a copper wire were developed. The possibility of using silylureas of various structures as effective surfactants used in the electrodeposition of the tin-indium alloy is shown. The operational characteristics of the obtained wire were investigated, including the wire diameter, coating thickness, tensile strength, electrical resistance, and direct current electrical resistivity.
format article
author K. Yu. Ivanova
M. V. Kuzmin
L. G. Rogozhina
A. O. Patianova
V. L. Semenov
R. I. Alexandrov
author_facet K. Yu. Ivanova
M. V. Kuzmin
L. G. Rogozhina
A. O. Patianova
V. L. Semenov
R. I. Alexandrov
author_sort K. Yu. Ivanova
title Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
title_short Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
title_full Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
title_fullStr Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
title_full_unstemmed Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
title_sort synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
publisher Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
publishDate 2021
url https://doaj.org/article/442fc4f1b40446f0ba6c7921307dc757
work_keys_str_mv AT kyuivanova synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy
AT mvkuzmin synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy
AT lgrogozhina synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy
AT aopatianova synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy
AT vlsemenov synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy
AT rialexandrov synthesisandresearchofpolyfunctionalsilylureasusedinelectricdepositionoftinindiumalloy
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