Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode

Advanced poly(O-Toluidine) Sn(II) silicotungstate (POTSn(II)SiO2WO3) ternary nanocomposite synthesized by the extremely well-known simple sol–gel method. We have selected a low-cost o-toluidine monomer initiator and abundantly available metal of divalent tin with the silicon tungstate moieties that...

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Autores principales:	Anish Khan, Imran Khan, Abdullah M. Asiri
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Conducting polymer Nanocomposite FT-IR Ion-exchangers Host–guest system Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/44444312f3744a3c9748e514eb883402
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spelling	oai:doaj.org-article:44444312f3744a3c9748e514eb8834022021-11-20T04:57:27ZPreparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode1319-610310.1016/j.jscs.2021.101385https://doaj.org/article/44444312f3744a3c9748e514eb8834022021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1319610321001903https://doaj.org/toc/1319-6103Advanced poly(O-Toluidine) Sn(II) silicotungstate (POTSn(II)SiO2WO3) ternary nanocomposite synthesized by the extremely well-known simple sol–gel method. We have selected a low-cost o-toluidine monomer initiator and abundantly available metal of divalent tin with the silicon tungstate moieties that may work as the exchange sites for the metal ions. The poly(O-toluidine) Sn(II) silicotungstate was prepared by the oxidative polymerization of o-toluidine by potassium persulphate in situ mixings of the Sn(II) tungstate prepared in the separate conical flask at 5 pH. The obtained composite was characterized by various spectrophotometric techniques viz, SEM-EDX, XRD, TGA, FTIR, and its physicochemical characterization was carried out by determining its potential as an ion-selective membrane electrode. The ion-selective membrane was prepared and characterized for, porosity, swelling, and thickness. Based on high porosity and low thickness, the membrane was selected for further studies for the preparation of the selective membrane electrode and found selective for Cd2+. Based on the calibration curve, the Nernstian response was found near the Nernstian response (29.74), good pH range, and broad selectivity range of the metal ion. This ion-selective membrane electrode would be utilized for the determination of metal in unknown samples.Anish KhanImran KhanAbdullah M. AsiriElsevierarticleConducting polymerNanocompositeFT-IRIon-exchangersHost–guest systemChemistryQD1-999ENJournal of Saudi Chemical Society, Vol 25, Iss 12, Pp 101385- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Conducting polymer Nanocomposite FT-IR Ion-exchangers Host–guest system Chemistry QD1-999
spellingShingle	Conducting polymer Nanocomposite FT-IR Ion-exchangers Host–guest system Chemistry QD1-999 Anish Khan Imran Khan Abdullah M. Asiri Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode
description	Advanced poly(O-Toluidine) Sn(II) silicotungstate (POTSn(II)SiO2WO3) ternary nanocomposite synthesized by the extremely well-known simple sol–gel method. We have selected a low-cost o-toluidine monomer initiator and abundantly available metal of divalent tin with the silicon tungstate moieties that may work as the exchange sites for the metal ions. The poly(O-toluidine) Sn(II) silicotungstate was prepared by the oxidative polymerization of o-toluidine by potassium persulphate in situ mixings of the Sn(II) tungstate prepared in the separate conical flask at 5 pH. The obtained composite was characterized by various spectrophotometric techniques viz, SEM-EDX, XRD, TGA, FTIR, and its physicochemical characterization was carried out by determining its potential as an ion-selective membrane electrode. The ion-selective membrane was prepared and characterized for, porosity, swelling, and thickness. Based on high porosity and low thickness, the membrane was selected for further studies for the preparation of the selective membrane electrode and found selective for Cd2+. Based on the calibration curve, the Nernstian response was found near the Nernstian response (29.74), good pH range, and broad selectivity range of the metal ion. This ion-selective membrane electrode would be utilized for the determination of metal in unknown samples.
format	article
author	Anish Khan Imran Khan Abdullah M. Asiri
author_facet	Anish Khan Imran Khan Abdullah M. Asiri
author_sort	Anish Khan
title	Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode
title_short	Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode
title_full	Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode
title_fullStr	Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode
title_full_unstemmed	Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode
title_sort	preparation and characterization of new and novel poly-o-toluidine sn(ii) silicotungstate ternary nanocomposite and its environment application as indicator electrode
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/44444312f3744a3c9748e514eb883402
work_keys_str_mv	AT anishkhan preparationandcharacterizationofnewandnovelpolyotoluidinesniisilicotungstateternarynanocompositeanditsenvironmentapplicationasindicatorelectrode AT imrankhan preparationandcharacterizationofnewandnovelpolyotoluidinesniisilicotungstateternarynanocompositeanditsenvironmentapplicationasindicatorelectrode AT abdullahmasiri preparationandcharacterizationofnewandnovelpolyotoluidinesniisilicotungstateternarynanocompositeanditsenvironmentapplicationasindicatorelectrode
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Preparation and characterization of new and novel Poly-o-Toluidine Sn(II) silicotungstate ternary nanocomposite and its environment application as indicator electrode

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