Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2
Modified polyvinylidene fluoride (PVDF) membranes were prepared by the phase inversion method via blending in situ formed nanosilver (Ag) and nanozirconium dioxide (ZrO2). Scanning electron microscopy of the membranes revealed that the surface pore size of the membranes was increased and distributed...
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De Gruyter
2021
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oai:doaj.org-article:445bd53ac2c243aea61d9502cad119232021-12-05T14:10:50ZHydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO22191-955010.1515/gps-2021-0050https://doaj.org/article/445bd53ac2c243aea61d9502cad119232021-08-01T00:00:00Zhttps://doi.org/10.1515/gps-2021-0050https://doaj.org/toc/2191-9550Modified polyvinylidene fluoride (PVDF) membranes were prepared by the phase inversion method via blending in situ formed nanosilver (Ag) and nanozirconium dioxide (ZrO2). Scanning electron microscopy of the membranes revealed that the surface pore size of the membranes was increased and distributed widely with the addition of modified nanosilver (Ag) and nanozirconium dioxide (ZrO2). The pores of the membrane were reduced due to excessive modification of the material when the content of zirconium dioxide was increased to 0.4%. XRD characterization showed that in situ synthesis of nanosilver (Ag) and nanozirconium dioxide (ZrO2) had been successfully blended in the membranes. The contact angle of the modified membrane ranged from 82.72° to 67.37°, which showed that the hydrophilic properties of the membrane were improved. The pure water flux of the modified membrane increased from 28.43 to 143.2 L/m2 h, indicating that the hydrophilicity of the modified membrane was enhanced significantly. The flux recovery rate of the modified membrane was obviously increased in the fouling experiment with BSA as the source of organic pollutants. The antimicrobial contamination of the membrane was greatly enhanced with the E. coli microbial contamination experiment.Lu YanjunMa YuxuanYang TongGuo JifengDe Gruyterarticlehydrophilic modificationpvdf membranein situ synthesisag with zirconium dioxide nanoparticlesantifoulingChemistryQD1-999ENGreen Processing and Synthesis, Vol 10, Iss 1, Pp 538-546 (2021) |
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hydrophilic modification pvdf membrane in situ synthesis ag with zirconium dioxide nanoparticles antifouling Chemistry QD1-999 |
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hydrophilic modification pvdf membrane in situ synthesis ag with zirconium dioxide nanoparticles antifouling Chemistry QD1-999 Lu Yanjun Ma Yuxuan Yang Tong Guo Jifeng Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2 |
description |
Modified polyvinylidene fluoride (PVDF) membranes were prepared by the phase inversion method via blending in situ formed nanosilver (Ag) and nanozirconium dioxide (ZrO2). Scanning electron microscopy of the membranes revealed that the surface pore size of the membranes was increased and distributed widely with the addition of modified nanosilver (Ag) and nanozirconium dioxide (ZrO2). The pores of the membrane were reduced due to excessive modification of the material when the content of zirconium dioxide was increased to 0.4%. XRD characterization showed that in situ synthesis of nanosilver (Ag) and nanozirconium dioxide (ZrO2) had been successfully blended in the membranes. The contact angle of the modified membrane ranged from 82.72° to 67.37°, which showed that the hydrophilic properties of the membrane were improved. The pure water flux of the modified membrane increased from 28.43 to 143.2 L/m2 h, indicating that the hydrophilicity of the modified membrane was enhanced significantly. The flux recovery rate of the modified membrane was obviously increased in the fouling experiment with BSA as the source of organic pollutants. The antimicrobial contamination of the membrane was greatly enhanced with the E. coli microbial contamination experiment. |
format |
article |
author |
Lu Yanjun Ma Yuxuan Yang Tong Guo Jifeng |
author_facet |
Lu Yanjun Ma Yuxuan Yang Tong Guo Jifeng |
author_sort |
Lu Yanjun |
title |
Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2 |
title_short |
Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2 |
title_full |
Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2 |
title_fullStr |
Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2 |
title_full_unstemmed |
Hydrophilic modification of PVDF membranes by in situ synthesis of nano-Ag with nano-ZrO2 |
title_sort |
hydrophilic modification of pvdf membranes by in situ synthesis of nano-ag with nano-zro2 |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/445bd53ac2c243aea61d9502cad11923 |
work_keys_str_mv |
AT luyanjun hydrophilicmodificationofpvdfmembranesbyinsitusynthesisofnanoagwithnanozro2 AT mayuxuan hydrophilicmodificationofpvdfmembranesbyinsitusynthesisofnanoagwithnanozro2 AT yangtong hydrophilicmodificationofpvdfmembranesbyinsitusynthesisofnanoagwithnanozro2 AT guojifeng hydrophilicmodificationofpvdfmembranesbyinsitusynthesisofnanoagwithnanozro2 |
_version_ |
1718371665095688192 |