Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides

Catalysts based on s-block elements offer exciting prospects for new reactivity, but their chemistry remain poorly understood. Here, both the catalytic activity of the dimeric magnesium tert-butylperoxide with β-diketiminate ligand as well as its transformation to a tetranuclear magnesium alkylperox...

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Autores principales:	Tomasz Pietrzak, Iwona Justyniak, Karolina Zelga, Krzysztof Nowak, Zbigniew Ochal, Janusz Lewiński
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/44b1bd58c050429581576213ff44321f
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spelling	oai:doaj.org-article:44b1bd58c050429581576213ff44321f2021-12-02T19:02:37ZTowards deeper understanding of multifaceted chemistry of magnesium alkylperoxides10.1038/s42004-021-00560-92399-3669https://doaj.org/article/44b1bd58c050429581576213ff44321f2021-08-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00560-9https://doaj.org/toc/2399-3669Catalysts based on s-block elements offer exciting prospects for new reactivity, but their chemistry remain poorly understood. Here, both the catalytic activity of the dimeric magnesium tert-butylperoxide with β-diketiminate ligand as well as its transformation to a tetranuclear magnesium alkylperoxide are shown.Tomasz PietrzakIwona JustyniakKarolina ZelgaKrzysztof NowakZbigniew OchalJanusz LewińskiNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Tomasz Pietrzak Iwona Justyniak Karolina Zelga Krzysztof Nowak Zbigniew Ochal Janusz Lewiński Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
description	Catalysts based on s-block elements offer exciting prospects for new reactivity, but their chemistry remain poorly understood. Here, both the catalytic activity of the dimeric magnesium tert-butylperoxide with β-diketiminate ligand as well as its transformation to a tetranuclear magnesium alkylperoxide are shown.
format	article
author	Tomasz Pietrzak Iwona Justyniak Karolina Zelga Krzysztof Nowak Zbigniew Ochal Janusz Lewiński
author_facet	Tomasz Pietrzak Iwona Justyniak Karolina Zelga Krzysztof Nowak Zbigniew Ochal Janusz Lewiński
author_sort	Tomasz Pietrzak
title	Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
title_short	Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
title_full	Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
title_fullStr	Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
title_full_unstemmed	Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
title_sort	towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/44b1bd58c050429581576213ff44321f
work_keys_str_mv	AT tomaszpietrzak towardsdeeperunderstandingofmultifacetedchemistryofmagnesiumalkylperoxides AT iwonajustyniak towardsdeeperunderstandingofmultifacetedchemistryofmagnesiumalkylperoxides AT karolinazelga towardsdeeperunderstandingofmultifacetedchemistryofmagnesiumalkylperoxides AT krzysztofnowak towardsdeeperunderstandingofmultifacetedchemistryofmagnesiumalkylperoxides AT zbigniewochal towardsdeeperunderstandingofmultifacetedchemistryofmagnesiumalkylperoxides AT januszlewinski towardsdeeperunderstandingofmultifacetedchemistryofmagnesiumalkylperoxides
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Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxides

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