Lead-free hybrid perovskite N(CH3)4SnI3 with robust ferroelectricity induced by large and non-polar N(CH3)4 + molecular cation

The ferroelectricity in hybrid perovskite CH3NH3PbI3 is under debate. Here, the authors predict a Pb-free hybrid perovskite N(CH3)4SnI3 with non-polar molecular cation N(CH3)4+ showing strong ferroelectricity, good stability, and high visible-light absorption, ideal for high-efficiency solar cells.

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Detalles Bibliográficos
Autores principales: Hai Wei, Yali Yang, Shiyou Chen, H. J. Xiang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/4511ef1944134d53957695c7be5371f4
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Sumario:The ferroelectricity in hybrid perovskite CH3NH3PbI3 is under debate. Here, the authors predict a Pb-free hybrid perovskite N(CH3)4SnI3 with non-polar molecular cation N(CH3)4+ showing strong ferroelectricity, good stability, and high visible-light absorption, ideal for high-efficiency solar cells.