Nickel-aluminium pincer complexes undergo cooperative bond activation

Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.

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Detalles Bibliográficos
Autor principal:	Andrew J. Bissette
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/45192c9c39b14f9ca8165180aaf45b74
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

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spelling	oai:doaj.org-article:45192c9c39b14f9ca8165180aaf45b742021-12-02T15:49:33ZNickel-aluminium pincer complexes undergo cooperative bond activation10.1038/s42004-021-00519-w2399-3669https://doaj.org/article/45192c9c39b14f9ca8165180aaf45b742021-05-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00519-whttps://doaj.org/toc/2399-3669Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.Andrew J. BissetteNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-2 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Andrew J. Bissette Nickel-aluminium pincer complexes undergo cooperative bond activation
description	Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.
format	article
author	Andrew J. Bissette
author_facet	Andrew J. Bissette
author_sort	Andrew J. Bissette
title	Nickel-aluminium pincer complexes undergo cooperative bond activation
title_short	Nickel-aluminium pincer complexes undergo cooperative bond activation
title_full	Nickel-aluminium pincer complexes undergo cooperative bond activation
title_fullStr	Nickel-aluminium pincer complexes undergo cooperative bond activation
title_full_unstemmed	Nickel-aluminium pincer complexes undergo cooperative bond activation
title_sort	nickel-aluminium pincer complexes undergo cooperative bond activation
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/45192c9c39b14f9ca8165180aaf45b74
work_keys_str_mv	AT andrewjbissette nickelaluminiumpincercomplexesundergocooperativebondactivation
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Nickel-aluminium pincer complexes undergo cooperative bond activation

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