Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste

In this study, hemicellulose-based polymeric gel films were synthesized using the free radical polymerization mechanism. Hemicellulose was obtained from tea leaf brewing waste by using delignification process. Polymeric gel films were produced in accordance with solution-casting technique. The effec...

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Autores principales: Taşar Şeyda, Özer Ahmet
Formato: article
Lenguaje:EN
Publicado: Association of the Chemical Engineers of Serbia 2021
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Acceso en línea:https://doaj.org/article/456d387792444b8d948745264c628369
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spelling oai:doaj.org-article:456d387792444b8d948745264c6283692021-11-10T07:27:42ZSynthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste1451-93722217-743410.2298/CICEQ200810045Thttps://doaj.org/article/456d387792444b8d948745264c6283692021-01-01T00:00:00Zhttp://www.doiserbia.nb.rs/img/doi/1451-9372/2021/1451-93722000045T.pdfhttps://doaj.org/toc/1451-9372https://doaj.org/toc/2217-7434In this study, hemicellulose-based polymeric gel films were synthesized using the free radical polymerization mechanism. Hemicellulose was obtained from tea leaf brewing waste by using delignification process. Polymeric gel films were produced in accordance with solution-casting technique. The effects of synthesis parameters were investigated on the structure and properties of gel films. For this purpose, the hemicellulose-based synthesized gel films were characterized by analytical test. Experimental results indicated that hemicellulose- based gel films absorbed moisture at the rate of maximum 1% in 100% relative humidity environment. The lowest water vapor permeability (WVP) value was measured to be 5.88×10-10 g/(s Pa m), for the hemicellulose-based film including chitosan. The average solubility values of the produced polymeric films varied between approximately 0.4 and 1.8%. It was observed that the optical transparency of hemicellulose-based polymeric gel films changed from about 45 to 65% and the opacity/thickness values were from 0.0027 to 0.0011 μm-1. As a result, it was found that the physicochemical and morphological properties of the synthesized films are greatly influenced by the composition of the films.Taşar ŞeydaÖzer AhmetAssociation of the Chemical Engineers of Serbiaarticlebiodegradablehemicellulosepolymergel filmcharacterizationChemical engineeringTP155-156Chemical industriesHD9650-9663ENChemical Industry and Chemical Engineering Quarterly, Vol 27, Iss 3, Pp 265-277 (2021)
institution DOAJ
collection DOAJ
language EN
topic biodegradable
hemicellulose
polymer
gel film
characterization
Chemical engineering
TP155-156
Chemical industries
HD9650-9663
spellingShingle biodegradable
hemicellulose
polymer
gel film
characterization
Chemical engineering
TP155-156
Chemical industries
HD9650-9663
Taşar Şeyda
Özer Ahmet
Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
description In this study, hemicellulose-based polymeric gel films were synthesized using the free radical polymerization mechanism. Hemicellulose was obtained from tea leaf brewing waste by using delignification process. Polymeric gel films were produced in accordance with solution-casting technique. The effects of synthesis parameters were investigated on the structure and properties of gel films. For this purpose, the hemicellulose-based synthesized gel films were characterized by analytical test. Experimental results indicated that hemicellulose- based gel films absorbed moisture at the rate of maximum 1% in 100% relative humidity environment. The lowest water vapor permeability (WVP) value was measured to be 5.88×10-10 g/(s Pa m), for the hemicellulose-based film including chitosan. The average solubility values of the produced polymeric films varied between approximately 0.4 and 1.8%. It was observed that the optical transparency of hemicellulose-based polymeric gel films changed from about 45 to 65% and the opacity/thickness values were from 0.0027 to 0.0011 μm-1. As a result, it was found that the physicochemical and morphological properties of the synthesized films are greatly influenced by the composition of the films.
format article
author Taşar Şeyda
Özer Ahmet
author_facet Taşar Şeyda
Özer Ahmet
author_sort Taşar Şeyda
title Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
title_short Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
title_full Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
title_fullStr Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
title_full_unstemmed Synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
title_sort synthesis and characterization of hemicellulose-based polymeric gel film from tea leaf brewing waste
publisher Association of the Chemical Engineers of Serbia
publishDate 2021
url https://doaj.org/article/456d387792444b8d948745264c628369
work_keys_str_mv AT tasarseyda synthesisandcharacterizationofhemicellulosebasedpolymericgelfilmfromtealeafbrewingwaste
AT ozerahmet synthesisandcharacterizationofhemicellulosebasedpolymericgelfilmfromtealeafbrewingwaste
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