Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China

Abstract A number of condensate reservoirs with high concentrations of H2S have been discovered in the deep dolomite reservoirs of the lower Ordovician Yingshan Formation (O1y) in the Tazhong Uplift, where the formation water has a high pH value. In the O1y reservoir, the concentrations of Mg2+ and...

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Autores principales: Jin Su, Yu Wang, Xiao-Mei Wang, Kun He, Hai-Jun Yang, Hui-Tong Wang, Hua-Jian Wang, Bin Zhang, Ling Huang, Na Weng, Li-Na Bi, Zhi-Hua Xiao
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Publicado: KeAi Communications Co., Ltd. 2017
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spelling oai:doaj.org-article:4577340612fd465f871037b24b7794102021-12-02T08:01:37ZImpact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China10.1007/s12182-017-0176-z1672-51071995-8226https://doaj.org/article/4577340612fd465f871037b24b7794102017-07-01T00:00:00Zhttp://link.springer.com/article/10.1007/s12182-017-0176-zhttps://doaj.org/toc/1672-5107https://doaj.org/toc/1995-8226Abstract A number of condensate reservoirs with high concentrations of H2S have been discovered in the deep dolomite reservoirs of the lower Ordovician Yingshan Formation (O1y) in the Tazhong Uplift, where the formation water has a high pH value. In the O1y reservoir, the concentrations of Mg2+ and SO4 2− in the formation water are higher than those in the upper Ordovician formation. The concentration of H2S in the condensate reservoirs and the concentration of Mg2+ in the formation water correlate well in the O1y reservoirs of the Tazhong Uplift, which indicates a presumed thermochemical sulfate reduction (TSR) origin of H2S according to the oxidation theory of contact ion-pairs (CIPs). Besides, the pH values of the formation water are positively correlated with the concentration of H2S in the condensate reservoirs, which may indicate that high pH might be another factor to promote and maintain TSR. Oil–source correlation of biomarkers in the sulfuretted condensates indicates the Cambrian source rocks could be the origin of condensates. The formation water in the condensate reservoirs of O1y is similar to that in the Cambrian; therefore, the TSR of sulfate-CIPs likely occurred in the Cambrian. High H2S-bearing condensates are mainly located near the No. 1 Fault and NE-SW strike-slip faults, which are the major migration pathway of deep fluids in the Tazhong Uplift. The redox between sulfate-CIPs and hydrocarbons is the generation mechanism of H2S in the deep dolomite condensate reservoirs of the Tazhong Uplift. This finding should be helpful to predict the fluid properties of deep dolomite reservoirs.Jin SuYu WangXiao-Mei WangKun HeHai-Jun YangHui-Tong WangHua-Jian WangBin ZhangLing HuangNa WengLi-Na BiZhi-Hua XiaoKeAi Communications Co., Ltd.articleFormation waterSulfate-CIPsTSRCondensatesDolomite reservoirTarim basinScienceQPetrologyQE420-499ENPetroleum Science, Vol 14, Iss 3, Pp 507-519 (2017)
institution DOAJ
collection DOAJ
language EN
topic Formation water
Sulfate-CIPs
TSR
Condensates
Dolomite reservoir
Tarim basin
Science
Q
Petrology
QE420-499
spellingShingle Formation water
Sulfate-CIPs
TSR
Condensates
Dolomite reservoir
Tarim basin
Science
Q
Petrology
QE420-499
Jin Su
Yu Wang
Xiao-Mei Wang
Kun He
Hai-Jun Yang
Hui-Tong Wang
Hua-Jian Wang
Bin Zhang
Ling Huang
Na Weng
Li-Na Bi
Zhi-Hua Xiao
Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China
description Abstract A number of condensate reservoirs with high concentrations of H2S have been discovered in the deep dolomite reservoirs of the lower Ordovician Yingshan Formation (O1y) in the Tazhong Uplift, where the formation water has a high pH value. In the O1y reservoir, the concentrations of Mg2+ and SO4 2− in the formation water are higher than those in the upper Ordovician formation. The concentration of H2S in the condensate reservoirs and the concentration of Mg2+ in the formation water correlate well in the O1y reservoirs of the Tazhong Uplift, which indicates a presumed thermochemical sulfate reduction (TSR) origin of H2S according to the oxidation theory of contact ion-pairs (CIPs). Besides, the pH values of the formation water are positively correlated with the concentration of H2S in the condensate reservoirs, which may indicate that high pH might be another factor to promote and maintain TSR. Oil–source correlation of biomarkers in the sulfuretted condensates indicates the Cambrian source rocks could be the origin of condensates. The formation water in the condensate reservoirs of O1y is similar to that in the Cambrian; therefore, the TSR of sulfate-CIPs likely occurred in the Cambrian. High H2S-bearing condensates are mainly located near the No. 1 Fault and NE-SW strike-slip faults, which are the major migration pathway of deep fluids in the Tazhong Uplift. The redox between sulfate-CIPs and hydrocarbons is the generation mechanism of H2S in the deep dolomite condensate reservoirs of the Tazhong Uplift. This finding should be helpful to predict the fluid properties of deep dolomite reservoirs.
format article
author Jin Su
Yu Wang
Xiao-Mei Wang
Kun He
Hai-Jun Yang
Hui-Tong Wang
Hua-Jian Wang
Bin Zhang
Ling Huang
Na Weng
Li-Na Bi
Zhi-Hua Xiao
author_facet Jin Su
Yu Wang
Xiao-Mei Wang
Kun He
Hai-Jun Yang
Hui-Tong Wang
Hua-Jian Wang
Bin Zhang
Ling Huang
Na Weng
Li-Na Bi
Zhi-Hua Xiao
author_sort Jin Su
title Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China
title_short Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China
title_full Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China
title_fullStr Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China
title_full_unstemmed Impact of formation water on the generation of H2S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China
title_sort impact of formation water on the generation of h2s in condensate reservoirs: a case study from the deep ordovician in the tazhong uplift of the tarim basin, nw china
publisher KeAi Communications Co., Ltd.
publishDate 2017
url https://doaj.org/article/4577340612fd465f871037b24b779410
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