Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers

This study explores the possibility of transforming lignocellulose-rich agricultural waste materials into value-added products. Cellulose was extracted from an empty fruit bunch of oil palm and further modified into carboxymethyl cellulose (CMC), a water-soluble cellulose derivative. The CMC was the...

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Autores principales:	Cheyma Naceur Abouloula, Muhammad. Rizwan, Vidhya Selvanathan, Rosiyah Yahya, Khaled Althubeiti, Hend I. Alkhammash, Md. Akhtaruzzaman, A. Oueriagli
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	carboxymethyl cellulose glycerol polymer electrolyte ionic conductivity Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/45fa50041a984c3ea9c1c325c10e7e75
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spelling	oai:doaj.org-article:45fa50041a984c3ea9c1c325c10e7e752021-11-11T18:43:54ZTransformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers10.3390/polym132136852073-4360https://doaj.org/article/45fa50041a984c3ea9c1c325c10e7e752021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/21/3685https://doaj.org/toc/2073-4360This study explores the possibility of transforming lignocellulose-rich agricultural waste materials into value-added products. Cellulose was extracted from an empty fruit bunch of oil palm and further modified into carboxymethyl cellulose (CMC), a water-soluble cellulose derivative. The CMC was then employed as the polymeric content in fabrication of solid polymer electrolyte (SPE) films incorporated with lithium iodide. To enhance the ionic conductivity of the solid polymer electrolytes, the compositions were optimized with different amounts of glycerol as a plasticizing agent. The chemical and physical effects of plasticizer content on the film composition were studied by Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis. FTIR and XRD analysis confirmed the interaction plasticizer with the polymer matrix and the amorphous nature of fabricated SPEs. The highest ionic conductivity of 6.26 × 10<sup>−2</sup> S/cm was obtained with the addition of 25 wt % of glycerol. By fabricating solid polymer electrolytes from oil palm waste-derived cellulose, the sustainability of the materials can be retained while reducing the dependence on fossil fuel-derived materials in electrochemical devices.Cheyma Naceur AbouloulaMuhammad. RizwanVidhya SelvanathanRosiyah YahyaKhaled AlthubeitiHend I. AlkhammashMd. AkhtaruzzamanA. OueriagliMDPI AGarticlecarboxymethyl celluloseglycerolpolymer electrolyteionic conductivityOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3685, p 3685 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	carboxymethyl cellulose glycerol polymer electrolyte ionic conductivity Organic chemistry QD241-441
spellingShingle	carboxymethyl cellulose glycerol polymer electrolyte ionic conductivity Organic chemistry QD241-441 Cheyma Naceur Abouloula Muhammad. Rizwan Vidhya Selvanathan Rosiyah Yahya Khaled Althubeiti Hend I. Alkhammash Md. Akhtaruzzaman A. Oueriagli Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers
description	This study explores the possibility of transforming lignocellulose-rich agricultural waste materials into value-added products. Cellulose was extracted from an empty fruit bunch of oil palm and further modified into carboxymethyl cellulose (CMC), a water-soluble cellulose derivative. The CMC was then employed as the polymeric content in fabrication of solid polymer electrolyte (SPE) films incorporated with lithium iodide. To enhance the ionic conductivity of the solid polymer electrolytes, the compositions were optimized with different amounts of glycerol as a plasticizing agent. The chemical and physical effects of plasticizer content on the film composition were studied by Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis. FTIR and XRD analysis confirmed the interaction plasticizer with the polymer matrix and the amorphous nature of fabricated SPEs. The highest ionic conductivity of 6.26 × 10<sup>−2</sup> S/cm was obtained with the addition of 25 wt % of glycerol. By fabricating solid polymer electrolytes from oil palm waste-derived cellulose, the sustainability of the materials can be retained while reducing the dependence on fossil fuel-derived materials in electrochemical devices.
format	article
author	Cheyma Naceur Abouloula Muhammad. Rizwan Vidhya Selvanathan Rosiyah Yahya Khaled Althubeiti Hend I. Alkhammash Md. Akhtaruzzaman A. Oueriagli
author_facet	Cheyma Naceur Abouloula Muhammad. Rizwan Vidhya Selvanathan Rosiyah Yahya Khaled Althubeiti Hend I. Alkhammash Md. Akhtaruzzaman A. Oueriagli
author_sort	Cheyma Naceur Abouloula
title	Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers
title_short	Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers
title_full	Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers
title_fullStr	Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers
title_full_unstemmed	Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers
title_sort	transformation of oil palm waste-derived cellulose into solid polymer electrolytes: investigating the crucial role of plasticizers
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/45fa50041a984c3ea9c1c325c10e7e75
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Transformation of Oil Palm Waste-Derived Cellulose into Solid Polymer Electrolytes: Investigating the Crucial Role of Plasticizers

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