On the limitations in assessing stability of oxygen evolution catalysts using aqueous model electrochemical cells

Dissolution of Ir catalysts varies widely between PEM water electrolysers and aqueous electrolytes. Here, we systematically investigate this finding and propose that stabilization of the catalysts over time and overestimated ionomer acidity are the main contributors to the dissolution discrepancy.

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Autores principales: Julius Knöppel, Maximilian Möckl, Daniel Escalera-López, Kevin Stojanovski, Markus Bierling, Thomas Böhm, Simon Thiele, Matthias Rzepka, Serhiy Cherevko
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/45fe91fd42294b50b5411ac624962557
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Sumario:Dissolution of Ir catalysts varies widely between PEM water electrolysers and aqueous electrolytes. Here, we systematically investigate this finding and propose that stabilization of the catalysts over time and overestimated ionomer acidity are the main contributors to the dissolution discrepancy.