Methyl groups as widespread Lewis bases in noncovalent interactions

Tetrel bonds are noncovalent interactions between electron donors and group 14 elements; in these situations, C(sp3) atoms can act as Lewis acids, accepting electron density. Here, the authors show that methyl groups, when bound to atoms less electronegative than carbon, can participate in noncovale...

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Autores principales:	Oliver Loveday, Jorge Echeverría
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4620f4957e364d4195c2fc6169ff8a39
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spelling	oai:doaj.org-article:4620f4957e364d4195c2fc6169ff8a392021-12-02T15:10:55ZMethyl groups as widespread Lewis bases in noncovalent interactions10.1038/s41467-021-25314-y2041-1723https://doaj.org/article/4620f4957e364d4195c2fc6169ff8a392021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25314-yhttps://doaj.org/toc/2041-1723Tetrel bonds are noncovalent interactions between electron donors and group 14 elements; in these situations, C(sp3) atoms can act as Lewis acids, accepting electron density. Here, the authors show that methyl groups, when bound to atoms less electronegative than carbon, can participate in noncovalent interactions as electron density donors.Oliver LovedayJorge EcheverríaNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Oliver Loveday Jorge Echeverría Methyl groups as widespread Lewis bases in noncovalent interactions
description	Tetrel bonds are noncovalent interactions between electron donors and group 14 elements; in these situations, C(sp3) atoms can act as Lewis acids, accepting electron density. Here, the authors show that methyl groups, when bound to atoms less electronegative than carbon, can participate in noncovalent interactions as electron density donors.
format	article
author	Oliver Loveday Jorge Echeverría
author_facet	Oliver Loveday Jorge Echeverría
author_sort	Oliver Loveday
title	Methyl groups as widespread Lewis bases in noncovalent interactions
title_short	Methyl groups as widespread Lewis bases in noncovalent interactions
title_full	Methyl groups as widespread Lewis bases in noncovalent interactions
title_fullStr	Methyl groups as widespread Lewis bases in noncovalent interactions
title_full_unstemmed	Methyl groups as widespread Lewis bases in noncovalent interactions
title_sort	methyl groups as widespread lewis bases in noncovalent interactions
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/4620f4957e364d4195c2fc6169ff8a39
work_keys_str_mv	AT oliverloveday methylgroupsaswidespreadlewisbasesinnoncovalentinteractions AT jorgeecheverria methylgroupsaswidespreadlewisbasesinnoncovalentinteractions
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Methyl groups as widespread Lewis bases in noncovalent interactions

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