Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics

Organohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums. Here, the authors report that TEMPO and its derivatives are active catalysts for electrophilic halog...

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Auteurs principaux:	Weijin Wang, Xinyao Li, Xiaoxue Yang, Lingsheng Ai, Zhiwen Gong, Ning Jiao, Song Song
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2021
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/467a14265b2746ddaa418cf930f0abee
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spelling	oai:doaj.org-article:467a14265b2746ddaa418cf930f0abee2021-12-02T17:12:20ZOxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics10.1038/s41467-021-24174-w2041-1723https://doaj.org/article/467a14265b2746ddaa418cf930f0abee2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24174-whttps://doaj.org/toc/2041-1723Organohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums. Here, the authors report that TEMPO and its derivatives are active catalysts for electrophilic halogenation of olefins, alkynes and aromatics, under mild reaction conditions and with good functional group tolerance.Weijin WangXinyao LiXiaoxue YangLingsheng AiZhiwen GongNing JiaoSong SongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Weijin Wang Xinyao Li Xiaoxue Yang Lingsheng Ai Zhiwen Gong Ning Jiao Song Song Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
description	Organohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums. Here, the authors report that TEMPO and its derivatives are active catalysts for electrophilic halogenation of olefins, alkynes and aromatics, under mild reaction conditions and with good functional group tolerance.
format	article
author	Weijin Wang Xinyao Li Xiaoxue Yang Lingsheng Ai Zhiwen Gong Ning Jiao Song Song
author_facet	Weijin Wang Xinyao Li Xiaoxue Yang Lingsheng Ai Zhiwen Gong Ning Jiao Song Song
author_sort	Weijin Wang
title	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_short	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_full	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_fullStr	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_full_unstemmed	Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
title_sort	oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/467a14265b2746ddaa418cf930f0abee
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_version_	1718381430198763520

Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics

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