Asymmetric remote C-H borylation of internal alkenes via alkene isomerization

Sequential alkene isomerization/functionalization enables enantioselective transformations of remote C–H bonds. Here, the authors report a chiral cobalt catalytic system for the highly enantioselective, remote C–H borylation of internal alkenes via an isomerization/hydroboration sequence.

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Detalles Bibliográficos
Autores principales:	Xu Chen, Zhaoyang Cheng, Jun Guo, Zhan Lu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/46dca3b2e3ec4606821b361f5f6543aa
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spelling	oai:doaj.org-article:46dca3b2e3ec4606821b361f5f6543aa2021-12-02T14:40:07ZAsymmetric remote C-H borylation of internal alkenes via alkene isomerization10.1038/s41467-018-06240-y2041-1723https://doaj.org/article/46dca3b2e3ec4606821b361f5f6543aa2018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06240-yhttps://doaj.org/toc/2041-1723Sequential alkene isomerization/functionalization enables enantioselective transformations of remote C–H bonds. Here, the authors report a chiral cobalt catalytic system for the highly enantioselective, remote C–H borylation of internal alkenes via an isomerization/hydroboration sequence.Xu ChenZhaoyang ChengJun GuoZhan LuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xu Chen Zhaoyang Cheng Jun Guo Zhan Lu Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
description	Sequential alkene isomerization/functionalization enables enantioselective transformations of remote C–H bonds. Here, the authors report a chiral cobalt catalytic system for the highly enantioselective, remote C–H borylation of internal alkenes via an isomerization/hydroboration sequence.
format	article
author	Xu Chen Zhaoyang Cheng Jun Guo Zhan Lu
author_facet	Xu Chen Zhaoyang Cheng Jun Guo Zhan Lu
author_sort	Xu Chen
title	Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
title_short	Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
title_full	Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
title_fullStr	Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
title_full_unstemmed	Asymmetric remote C-H borylation of internal alkenes via alkene isomerization
title_sort	asymmetric remote c-h borylation of internal alkenes via alkene isomerization
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/46dca3b2e3ec4606821b361f5f6543aa
work_keys_str_mv	AT xuchen asymmetricremotechborylationofinternalalkenesviaalkeneisomerization AT zhaoyangcheng asymmetricremotechborylationofinternalalkenesviaalkeneisomerization AT junguo asymmetricremotechborylationofinternalalkenesviaalkeneisomerization AT zhanlu asymmetricremotechborylationofinternalalkenesviaalkeneisomerization
_version_	1718390411165171712

Asymmetric remote C-H borylation of internal alkenes via alkene isomerization

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