Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model

The Landau-Zener formula is a semiclassical model describing nonadiabatic transitions, but its range of validity in approaching the adiabatic regime had not been verified. The authors investigate electron transfer reactions in a series of mixed-valence complexes spanning the nonadiabatic throughout...

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Autores principales:	Guang Yuan Zhu, Yi Qin, Miao Meng, Suman Mallick, Hang Gao, Xiaoli Chen, Tao Cheng, Ying Ning Tan, Xuan Xiao, Mei Juan Han, Mei Fang Sun, Chun Y. Liu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/47312dc4da554fe5917a4d68b2cfa680
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spelling	oai:doaj.org-article:47312dc4da554fe5917a4d68b2cfa6802021-12-02T14:19:04ZCrossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model10.1038/s41467-020-20557-72041-1723https://doaj.org/article/47312dc4da554fe5917a4d68b2cfa6802021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20557-7https://doaj.org/toc/2041-1723The Landau-Zener formula is a semiclassical model describing nonadiabatic transitions, but its range of validity in approaching the adiabatic regime had not been verified. The authors investigate electron transfer reactions in a series of mixed-valence complexes spanning the nonadiabatic throughout the adiabatic limit, and show that the model is valid in a broader range of conditions than previously expected.Guang Yuan ZhuYi QinMiao MengSuman MallickHang GaoXiaoli ChenTao ChengYing Ning TanXuan XiaoMei Juan HanMei Fang SunChun Y. LiuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Guang Yuan Zhu Yi Qin Miao Meng Suman Mallick Hang Gao Xiaoli Chen Tao Cheng Ying Ning Tan Xuan Xiao Mei Juan Han Mei Fang Sun Chun Y. Liu Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model
description	The Landau-Zener formula is a semiclassical model describing nonadiabatic transitions, but its range of validity in approaching the adiabatic regime had not been verified. The authors investigate electron transfer reactions in a series of mixed-valence complexes spanning the nonadiabatic throughout the adiabatic limit, and show that the model is valid in a broader range of conditions than previously expected.
format	article
author	Guang Yuan Zhu Yi Qin Miao Meng Suman Mallick Hang Gao Xiaoli Chen Tao Cheng Ying Ning Tan Xuan Xiao Mei Juan Han Mei Fang Sun Chun Y. Liu
author_facet	Guang Yuan Zhu Yi Qin Miao Meng Suman Mallick Hang Gao Xiaoli Chen Tao Cheng Ying Ning Tan Xuan Xiao Mei Juan Han Mei Fang Sun Chun Y. Liu
author_sort	Guang Yuan Zhu
title	Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model
title_short	Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model
title_full	Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model
title_fullStr	Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model
title_full_unstemmed	Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model
title_sort	crossover between the adiabatic and nonadiabatic electron transfer limits in the landau-zener model
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/47312dc4da554fe5917a4d68b2cfa680
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Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model

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