Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour

The rapid growth in the field of metal-organic frameworks (MOFs) over recent years has highlighted their high potential in a variety of applications. For biological and environmental applications MOFs with low toxicity are vitally important to avoid any harmful effects. For this reason, Ca-based MOF...

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Autores principales:	Russell M. Main, David B. Cordes, Aamod V. Desai, Alexandra M. Z. Slawin, Paul Wheatley, A. Robert Armstrong, Russell E. Morris
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	MOF calcium MOF electrochemistry scXRD VTXRD bioMOF Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/4747bea667f94e1dae29229328c6c224
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spelling	oai:doaj.org-article:4747bea667f94e1dae29229328c6c2242021-11-25T18:29:25ZSolvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour10.3390/molecules262270481420-3049https://doaj.org/article/4747bea667f94e1dae29229328c6c2242021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/7048https://doaj.org/toc/1420-3049The rapid growth in the field of metal-organic frameworks (MOFs) over recent years has highlighted their high potential in a variety of applications. For biological and environmental applications MOFs with low toxicity are vitally important to avoid any harmful effects. For this reason, Ca-based MOFs are highly desirable owing to their low cost and high biocompatibility. Useful Ca MOFs are still rare owing to the ionic character and large size of the Ca<sup>2+</sup> ion tending to produce dense phases. Presented here is a novel Ca-based MOF containing 2,3-dihyrdoxyterephthalate (2,3-dhtp) linkers Ca(2,3-dhtp)(H<sub>2</sub>O) (SIMOF-4). The material undergoes a phase transformation on heating, which can be followed by variable temperature powder X-ray diffraction. The structure of the high temperature form was obtained using single-crystal X-ray diffraction. The electrochemical properties of SIMOF-4 were also investigated for use in a Na ion battery.Russell M. MainDavid B. CordesAamod V. DesaiAlexandra M. Z. SlawinPaul WheatleyA. Robert ArmstrongRussell E. MorrisMDPI AGarticleMOFcalcium MOFelectrochemistryscXRDVTXRDbioMOFOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 7048, p 7048 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	MOF calcium MOF electrochemistry scXRD VTXRD bioMOF Organic chemistry QD241-441
spellingShingle	MOF calcium MOF electrochemistry scXRD VTXRD bioMOF Organic chemistry QD241-441 Russell M. Main David B. Cordes Aamod V. Desai Alexandra M. Z. Slawin Paul Wheatley A. Robert Armstrong Russell E. Morris Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
description	The rapid growth in the field of metal-organic frameworks (MOFs) over recent years has highlighted their high potential in a variety of applications. For biological and environmental applications MOFs with low toxicity are vitally important to avoid any harmful effects. For this reason, Ca-based MOFs are highly desirable owing to their low cost and high biocompatibility. Useful Ca MOFs are still rare owing to the ionic character and large size of the Ca<sup>2+</sup> ion tending to produce dense phases. Presented here is a novel Ca-based MOF containing 2,3-dihyrdoxyterephthalate (2,3-dhtp) linkers Ca(2,3-dhtp)(H<sub>2</sub>O) (SIMOF-4). The material undergoes a phase transformation on heating, which can be followed by variable temperature powder X-ray diffraction. The structure of the high temperature form was obtained using single-crystal X-ray diffraction. The electrochemical properties of SIMOF-4 were also investigated for use in a Na ion battery.
format	article
author	Russell M. Main David B. Cordes Aamod V. Desai Alexandra M. Z. Slawin Paul Wheatley A. Robert Armstrong Russell E. Morris
author_facet	Russell M. Main David B. Cordes Aamod V. Desai Alexandra M. Z. Slawin Paul Wheatley A. Robert Armstrong Russell E. Morris
author_sort	Russell M. Main
title	Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
title_short	Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
title_full	Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
title_fullStr	Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
title_full_unstemmed	Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
title_sort	solvothermal synthesis of a novel calcium metal-organic framework: high temperature and electrochemical behaviour
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/4747bea667f94e1dae29229328c6c224
work_keys_str_mv	AT russellmmain solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour AT davidbcordes solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour AT aamodvdesai solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour AT alexandramzslawin solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour AT paulwheatley solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour AT arobertarmstrong solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour AT russellemorris solvothermalsynthesisofanovelcalciummetalorganicframeworkhightemperatureandelectrochemicalbehaviour
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Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour

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