Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines

While nitrile hydrogenation may provide an appealing means to obtain secondary amines, poor selectivity plagues heterogeneous catalysts. Here, authors report single-atom palladium on nickel catalysts to afford high yields of secondary amines from a broad range of parent nitriles.

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Autores principales:	Hengwei Wang, Qiquan Luo, Wei Liu, Yue Lin, Qiaoqiao Guan, Xusheng Zheng, Haibin Pan, Junfa Zhu, Zhihu Sun, Shiqiang Wei, Jinlong Yang, Junling Lu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/47ef252e42574bfaa919094b1c7c1451
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spelling	oai:doaj.org-article:47ef252e42574bfaa919094b1c7c14512021-12-02T16:57:52ZQuasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines10.1038/s41467-019-12993-x2041-1723https://doaj.org/article/47ef252e42574bfaa919094b1c7c14512019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12993-xhttps://doaj.org/toc/2041-1723While nitrile hydrogenation may provide an appealing means to obtain secondary amines, poor selectivity plagues heterogeneous catalysts. Here, authors report single-atom palladium on nickel catalysts to afford high yields of secondary amines from a broad range of parent nitriles.Hengwei WangQiquan LuoWei LiuYue LinQiaoqiao GuanXusheng ZhengHaibin PanJunfa ZhuZhihu SunShiqiang WeiJinlong YangJunling LuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Hengwei Wang Qiquan Luo Wei Liu Yue Lin Qiaoqiao Guan Xusheng Zheng Haibin Pan Junfa Zhu Zhihu Sun Shiqiang Wei Jinlong Yang Junling Lu Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
description	While nitrile hydrogenation may provide an appealing means to obtain secondary amines, poor selectivity plagues heterogeneous catalysts. Here, authors report single-atom palladium on nickel catalysts to afford high yields of secondary amines from a broad range of parent nitriles.
format	article
author	Hengwei Wang Qiquan Luo Wei Liu Yue Lin Qiaoqiao Guan Xusheng Zheng Haibin Pan Junfa Zhu Zhihu Sun Shiqiang Wei Jinlong Yang Junling Lu
author_facet	Hengwei Wang Qiquan Luo Wei Liu Yue Lin Qiaoqiao Guan Xusheng Zheng Haibin Pan Junfa Zhu Zhihu Sun Shiqiang Wei Jinlong Yang Junling Lu
author_sort	Hengwei Wang
title	Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
title_short	Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
title_full	Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
title_fullStr	Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
title_full_unstemmed	Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
title_sort	quasi pd1ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/47ef252e42574bfaa919094b1c7c1451
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Quasi Pd1Ni single-atom surface alloy catalyst enables hydrogenation of nitriles to secondary amines

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