Ion exchange for halide perovskite: From nanocrystal to bulk materials
Abstract Halide perovskite, an ionic semiconductor, with the typically structural composition of ABX3 has become the extremely popular star in optoelectronics due to its superior photophysical properties and easily solution processing. In comparison with the traditional semiconductors, the perovskit...
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2021
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oai:doaj.org-article:47f07b60a6cc49cf8b7496e244e4cec02021-11-10T13:30:45ZIon exchange for halide perovskite: From nanocrystal to bulk materials2688-401110.1002/nano.202100084https://doaj.org/article/47f07b60a6cc49cf8b7496e244e4cec02021-11-01T00:00:00Zhttps://doi.org/10.1002/nano.202100084https://doaj.org/toc/2688-4011Abstract Halide perovskite, an ionic semiconductor, with the typically structural composition of ABX3 has become the extremely popular star in optoelectronics due to its superior photophysical properties and easily solution processing. In comparison with the traditional semiconductors, the perovskite possesses a low crystal formation energy with facile solution synthesis, which results into its soft and dynamic crystal lattice. Therefore, the post‐synthetic composition tuning via ion exchange has been proved to be an effective technique to introduce heteroatoms into perovskite lattice. In this review, we summarize the recent progress on ion exchange of halide perovskites, including mechanisms, methods, as well as different scales from low‐dimensional nanoscale to bulk crystal. Besides, we also briefly discuss the prospective of ion exchange for halide perovskites, and hope it benefit for the structural design and compositional optimization in halide perovskites for various optoelectronic applications.Haotian JiangSiqi CuiYu ChenHaizheng ZhongWiley-VCHarticlebulk materialshalide perovskiteion exchangenanocrystalpost‐synthesisMaterials of engineering and construction. Mechanics of materialsTA401-492ENNano Select, Vol 2, Iss 11, Pp 2040-2060 (2021) |
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bulk materials halide perovskite ion exchange nanocrystal post‐synthesis Materials of engineering and construction. Mechanics of materials TA401-492 |
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bulk materials halide perovskite ion exchange nanocrystal post‐synthesis Materials of engineering and construction. Mechanics of materials TA401-492 Haotian Jiang Siqi Cui Yu Chen Haizheng Zhong Ion exchange for halide perovskite: From nanocrystal to bulk materials |
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Abstract Halide perovskite, an ionic semiconductor, with the typically structural composition of ABX3 has become the extremely popular star in optoelectronics due to its superior photophysical properties and easily solution processing. In comparison with the traditional semiconductors, the perovskite possesses a low crystal formation energy with facile solution synthesis, which results into its soft and dynamic crystal lattice. Therefore, the post‐synthetic composition tuning via ion exchange has been proved to be an effective technique to introduce heteroatoms into perovskite lattice. In this review, we summarize the recent progress on ion exchange of halide perovskites, including mechanisms, methods, as well as different scales from low‐dimensional nanoscale to bulk crystal. Besides, we also briefly discuss the prospective of ion exchange for halide perovskites, and hope it benefit for the structural design and compositional optimization in halide perovskites for various optoelectronic applications. |
format |
article |
author |
Haotian Jiang Siqi Cui Yu Chen Haizheng Zhong |
author_facet |
Haotian Jiang Siqi Cui Yu Chen Haizheng Zhong |
author_sort |
Haotian Jiang |
title |
Ion exchange for halide perovskite: From nanocrystal to bulk materials |
title_short |
Ion exchange for halide perovskite: From nanocrystal to bulk materials |
title_full |
Ion exchange for halide perovskite: From nanocrystal to bulk materials |
title_fullStr |
Ion exchange for halide perovskite: From nanocrystal to bulk materials |
title_full_unstemmed |
Ion exchange for halide perovskite: From nanocrystal to bulk materials |
title_sort |
ion exchange for halide perovskite: from nanocrystal to bulk materials |
publisher |
Wiley-VCH |
publishDate |
2021 |
url |
https://doaj.org/article/47f07b60a6cc49cf8b7496e244e4cec0 |
work_keys_str_mv |
AT haotianjiang ionexchangeforhalideperovskitefromnanocrystaltobulkmaterials AT siqicui ionexchangeforhalideperovskitefromnanocrystaltobulkmaterials AT yuchen ionexchangeforhalideperovskitefromnanocrystaltobulkmaterials AT haizhengzhong ionexchangeforhalideperovskitefromnanocrystaltobulkmaterials |
_version_ |
1718439980559237120 |