Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins

Abstract A peroxo polyoxometalate‐based catalyst was synthesized, characterized, and employed as a catalyst in the epoxidation of olefins with hydrogen peroxide (H2O2). During the reaction, the insoluble catalyst became soluble and an emulsion formed to promote the epoxidation process. Then the emul...

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Autores principales:	Jinghui Wu, Hongwei Zheng, Chi Wang, Xianze Wang, Xiaohong Wang, Mingxin Huo
Formato:	article
Lenguaje:	EN
Publicado:	Wiley 2021
Materias:	Chemical technology TP1-1185 Materials of engineering and construction. Mechanics of materials TA401-492
Acceso en línea:	https://doaj.org/article/4822fe9e467c45c7921e3523fd53d7a9
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spelling	oai:doaj.org-article:4822fe9e467c45c7921e3523fd53d7a92021-11-25T05:05:59ZAmphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins1750-044310.1049/mna2.12090https://doaj.org/article/4822fe9e467c45c7921e3523fd53d7a92021-11-01T00:00:00Zhttps://doi.org/10.1049/mna2.12090https://doaj.org/toc/1750-0443Abstract A peroxo polyoxometalate‐based catalyst was synthesized, characterized, and employed as a catalyst in the epoxidation of olefins with hydrogen peroxide (H2O2). During the reaction, the insoluble catalyst became soluble and an emulsion formed to promote the epoxidation process. Then the emulsion broke and the catalyst precipitated for reuse easily.Jinghui WuHongwei ZhengChi WangXianze WangXiaohong WangMingxin HuoWileyarticleChemical technologyTP1-1185Materials of engineering and construction. Mechanics of materialsTA401-492ENMicro & Nano Letters, Vol 16, Iss 13, Pp 615-620 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemical technology TP1-1185 Materials of engineering and construction. Mechanics of materials TA401-492
spellingShingle	Chemical technology TP1-1185 Materials of engineering and construction. Mechanics of materials TA401-492 Jinghui Wu Hongwei Zheng Chi Wang Xianze Wang Xiaohong Wang Mingxin Huo Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
description	Abstract A peroxo polyoxometalate‐based catalyst was synthesized, characterized, and employed as a catalyst in the epoxidation of olefins with hydrogen peroxide (H2O2). During the reaction, the insoluble catalyst became soluble and an emulsion formed to promote the epoxidation process. Then the emulsion broke and the catalyst precipitated for reuse easily.
format	article
author	Jinghui Wu Hongwei Zheng Chi Wang Xianze Wang Xiaohong Wang Mingxin Huo
author_facet	Jinghui Wu Hongwei Zheng Chi Wang Xianze Wang Xiaohong Wang Mingxin Huo
author_sort	Jinghui Wu
title	Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
title_short	Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
title_full	Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
title_fullStr	Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
title_full_unstemmed	Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
title_sort	amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins
publisher	Wiley
publishDate	2021
url	https://doaj.org/article/4822fe9e467c45c7921e3523fd53d7a9
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_version_	1718414633547595776

Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins

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