Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide

In contrast to the well-established palladium-catalyzed version, the nickel-catalyzed carbonylative coupling is underdeveloped. Here the authors report a nickel-catalyzed allylic carbonylative coupling with alkyl zinc reagents, allowing for preparation of β,γ-unsaturated ketones in a linear-selectiv...

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Autores principales:	Yangyang Weng, Chenhuan Zhang, Zaiquan Tang, Mohini Shrestha, Wenyi Huang, Jingping Qu, Yifeng Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/48391b364a9c447590575e70c4ce619c
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spelling	oai:doaj.org-article:48391b364a9c447590575e70c4ce619c2021-12-02T14:40:39ZNickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide10.1038/s41467-020-14320-12041-1723https://doaj.org/article/48391b364a9c447590575e70c4ce619c2020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14320-1https://doaj.org/toc/2041-1723In contrast to the well-established palladium-catalyzed version, the nickel-catalyzed carbonylative coupling is underdeveloped. Here the authors report a nickel-catalyzed allylic carbonylative coupling with alkyl zinc reagents, allowing for preparation of β,γ-unsaturated ketones in a linear-selective fashion.Yangyang WengChenhuan ZhangZaiquan TangMohini ShresthaWenyi HuangJingping QuYifeng ChenNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yangyang Weng Chenhuan Zhang Zaiquan Tang Mohini Shrestha Wenyi Huang Jingping Qu Yifeng Chen Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
description	In contrast to the well-established palladium-catalyzed version, the nickel-catalyzed carbonylative coupling is underdeveloped. Here the authors report a nickel-catalyzed allylic carbonylative coupling with alkyl zinc reagents, allowing for preparation of β,γ-unsaturated ketones in a linear-selective fashion.
format	article
author	Yangyang Weng Chenhuan Zhang Zaiquan Tang Mohini Shrestha Wenyi Huang Jingping Qu Yifeng Chen
author_facet	Yangyang Weng Chenhuan Zhang Zaiquan Tang Mohini Shrestha Wenyi Huang Jingping Qu Yifeng Chen
author_sort	Yangyang Weng
title	Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
title_short	Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
title_full	Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
title_fullStr	Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
title_full_unstemmed	Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
title_sort	nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/48391b364a9c447590575e70c4ce619c
work_keys_str_mv	AT yangyangweng nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide AT chenhuanzhang nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide AT zaiquantang nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide AT mohinishrestha nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide AT wenyihuang nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide AT jingpingqu nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide AT yifengchen nickelcatalyzedallyliccarbonylativecouplingofalkylzincreagentswithtertbutylisocyanide
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Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide

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