Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide

In contrast to the well-established palladium-catalyzed version, the nickel-catalyzed carbonylative coupling is underdeveloped. Here the authors report a nickel-catalyzed allylic carbonylative coupling with alkyl zinc reagents, allowing for preparation of β,γ-unsaturated ketones in a linear-selectiv...

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Autores principales: Yangyang Weng, Chenhuan Zhang, Zaiquan Tang, Mohini Shrestha, Wenyi Huang, Jingping Qu, Yifeng Chen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/48391b364a9c447590575e70c4ce619c
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