Acid is a potential interferent in fluorescent sensing of chemical warfare agent vapors

Chemical warfare agents and simulants are commonly detected with fluorescent sensing materials containing nitrogen-based groups, however these groups’ basicity can cause false positives in the presence of acids. Here, the authors disentangle the response of pyridyl-containing sensing materials to ac...

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Autores principales: Shengqiang Fan, Genevieve H. Dennison, Nicholas FitzGerald, Paul L. Burn, Ian R. Gentle, Paul E. Shaw
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/484cdc3f057046d896adbe0631498b81
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Sumario:Chemical warfare agents and simulants are commonly detected with fluorescent sensing materials containing nitrogen-based groups, however these groups’ basicity can cause false positives in the presence of acids. Here, the authors disentangle the response of pyridyl-containing sensing materials to acid-containing and acid-free Sarin and simulants.