Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica

Recently, the research of innovative building materials is focused on applying supplementary materials in the form of micro- and nanopowders in cementitious composites due to the growing insistence on sustainable development. Considering above, in paper, a research on the effect of microsilica and S...

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Autores principales: Paweł Niewiadomski, Anna Karolak, Damian Stefaniuk, Aleksandra Królicka, Jacek Szymanowski, Łukasz Sadowski
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:48a5a4c9733942b4852928900530b6b22021-11-25T18:15:18ZCement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica10.3390/ma142269701996-1944https://doaj.org/article/48a5a4c9733942b4852928900530b6b22021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/6970https://doaj.org/toc/1996-1944Recently, the research of innovative building materials is focused on applying supplementary materials in the form of micro- and nanopowders in cementitious composites due to the growing insistence on sustainable development. Considering above, in paper, a research on the effect of microsilica and SiO<sub>2</sub> nanoparticles addition to cement paste, designed with Andreasen and Andersen (AA) packing density model (PDM), in terms of its physical and mechanical properties was conducted. Density, porosity, compressive strength, hardness, and modulus of indentation were investigated and compared regarding different amount of additives used in cement paste mixes. Microstructure of the obtained pastes was analyzed. The possibility of negative influence of alkali-silica reaction (ASR) on the mechanical properties of the obtained composites was analyzed. The results of the conducted investigations were discussed, and conclusions, also practical, were presented. The obtained results confirmed that the applied PDM may be an effective tool in cement paste design, when low porosity of prepared composite is required. On the other hand, the application of AA model did not bring satisfactory results of mechanical performance as expected, what was related, as shown by SEM imaging, with inhomogeneous dispersion of microsilica, and creation of agglomerates acting as reactive aggregates, what as a consequence caused ASR reaction, crack occurrence and lowered mechanical properties. Finally, the study found that the use of about 7.5% wt. of microsilica is the optimum in regards to obtain low porosity, while, to achieve improved mechanical properties, the use of 4 wt. % of microsilica seems to be optimal, in the case of tested cement pastes.Paweł NiewiadomskiAnna KarolakDamian StefaniukAleksandra KrólickaJacek SzymanowskiŁukasz SadowskiMDPI AGarticlepacking density modelmicrosilicananoparticlescement pastephysical propertiesmechanical propertiesTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6970, p 6970 (2021)
institution DOAJ
collection DOAJ
language EN
topic packing density model
microsilica
nanoparticles
cement paste
physical properties
mechanical properties
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle packing density model
microsilica
nanoparticles
cement paste
physical properties
mechanical properties
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Paweł Niewiadomski
Anna Karolak
Damian Stefaniuk
Aleksandra Królicka
Jacek Szymanowski
Łukasz Sadowski
Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica
description Recently, the research of innovative building materials is focused on applying supplementary materials in the form of micro- and nanopowders in cementitious composites due to the growing insistence on sustainable development. Considering above, in paper, a research on the effect of microsilica and SiO<sub>2</sub> nanoparticles addition to cement paste, designed with Andreasen and Andersen (AA) packing density model (PDM), in terms of its physical and mechanical properties was conducted. Density, porosity, compressive strength, hardness, and modulus of indentation were investigated and compared regarding different amount of additives used in cement paste mixes. Microstructure of the obtained pastes was analyzed. The possibility of negative influence of alkali-silica reaction (ASR) on the mechanical properties of the obtained composites was analyzed. The results of the conducted investigations were discussed, and conclusions, also practical, were presented. The obtained results confirmed that the applied PDM may be an effective tool in cement paste design, when low porosity of prepared composite is required. On the other hand, the application of AA model did not bring satisfactory results of mechanical performance as expected, what was related, as shown by SEM imaging, with inhomogeneous dispersion of microsilica, and creation of agglomerates acting as reactive aggregates, what as a consequence caused ASR reaction, crack occurrence and lowered mechanical properties. Finally, the study found that the use of about 7.5% wt. of microsilica is the optimum in regards to obtain low porosity, while, to achieve improved mechanical properties, the use of 4 wt. % of microsilica seems to be optimal, in the case of tested cement pastes.
format article
author Paweł Niewiadomski
Anna Karolak
Damian Stefaniuk
Aleksandra Królicka
Jacek Szymanowski
Łukasz Sadowski
author_facet Paweł Niewiadomski
Anna Karolak
Damian Stefaniuk
Aleksandra Królicka
Jacek Szymanowski
Łukasz Sadowski
author_sort Paweł Niewiadomski
title Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica
title_short Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica
title_full Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica
title_fullStr Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica
title_full_unstemmed Cement Paste Mixture Proportioning with Particle Packing Theory: An Ambiguous Effect of Microsilica
title_sort cement paste mixture proportioning with particle packing theory: an ambiguous effect of microsilica
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/48a5a4c9733942b4852928900530b6b2
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AT damianstefaniuk cementpastemixtureproportioningwithparticlepackingtheoryanambiguouseffectofmicrosilica
AT aleksandrakrolicka cementpastemixtureproportioningwithparticlepackingtheoryanambiguouseffectofmicrosilica
AT jacekszymanowski cementpastemixtureproportioningwithparticlepackingtheoryanambiguouseffectofmicrosilica
AT łukaszsadowski cementpastemixtureproportioningwithparticlepackingtheoryanambiguouseffectofmicrosilica
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