Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically.
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2017
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/498694facfba46f49228232c101d8f25 |
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| Sumario: | Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically. |
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