Chemical control of the viscoelastic properties of vinylogous urethane vitrimers

Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically.

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Autores principales: Wim Denissen, Martijn Droesbeke, Renaud Nicolaÿ, Ludwik Leibler, Johan M. Winne, Filip E. Du Prez
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/498694facfba46f49228232c101d8f25
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spelling oai:doaj.org-article:498694facfba46f49228232c101d8f252021-12-02T14:41:18ZChemical control of the viscoelastic properties of vinylogous urethane vitrimers10.1038/ncomms148572041-1723https://doaj.org/article/498694facfba46f49228232c101d8f252017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14857https://doaj.org/toc/2041-1723Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically.Wim DenissenMartijn DroesbekeRenaud NicolaÿLudwik LeiblerJohan M. WinneFilip E. Du PrezNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Wim Denissen
Martijn Droesbeke
Renaud Nicolaÿ
Ludwik Leibler
Johan M. Winne
Filip E. Du Prez
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
description Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically.
format article
author Wim Denissen
Martijn Droesbeke
Renaud Nicolaÿ
Ludwik Leibler
Johan M. Winne
Filip E. Du Prez
author_facet Wim Denissen
Martijn Droesbeke
Renaud Nicolaÿ
Ludwik Leibler
Johan M. Winne
Filip E. Du Prez
author_sort Wim Denissen
title Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
title_short Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
title_full Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
title_fullStr Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
title_full_unstemmed Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
title_sort chemical control of the viscoelastic properties of vinylogous urethane vitrimers
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/498694facfba46f49228232c101d8f25
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AT martijndroesbeke chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers
AT renaudnicolay chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers
AT ludwikleibler chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers
AT johanmwinne chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers
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