Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically.
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Nature Portfolio
2017
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oai:doaj.org-article:498694facfba46f49228232c101d8f252021-12-02T14:41:18ZChemical control of the viscoelastic properties of vinylogous urethane vitrimers10.1038/ncomms148572041-1723https://doaj.org/article/498694facfba46f49228232c101d8f252017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14857https://doaj.org/toc/2041-1723Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically.Wim DenissenMartijn DroesbekeRenaud NicolaÿLudwik LeiblerJohan M. WinneFilip E. Du PrezNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Wim Denissen Martijn Droesbeke Renaud Nicolaÿ Ludwik Leibler Johan M. Winne Filip E. Du Prez Chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
description |
Vitrimers are malleable networks based on thermally triggered associative exchange reactions and thus can be used for processing, recycling and self-healing materials. Here the authors show how acids and bases affect the exchange kinetics and in turn rationalize these effects mechanistically. |
format |
article |
author |
Wim Denissen Martijn Droesbeke Renaud Nicolaÿ Ludwik Leibler Johan M. Winne Filip E. Du Prez |
author_facet |
Wim Denissen Martijn Droesbeke Renaud Nicolaÿ Ludwik Leibler Johan M. Winne Filip E. Du Prez |
author_sort |
Wim Denissen |
title |
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
title_short |
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
title_full |
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
title_fullStr |
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
title_full_unstemmed |
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
title_sort |
chemical control of the viscoelastic properties of vinylogous urethane vitrimers |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/498694facfba46f49228232c101d8f25 |
work_keys_str_mv |
AT wimdenissen chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers AT martijndroesbeke chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers AT renaudnicolay chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers AT ludwikleibler chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers AT johanmwinne chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers AT filipeduprez chemicalcontroloftheviscoelasticpropertiesofvinylogousurethanevitrimers |
_version_ |
1718389927443431424 |