One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries

Tin dioxide (SnO<sub>2</sub>)-based materials, as anode materials for lithium-ion batteries (LIBs), have been attracting growing research attention due to the high theoretical specific capacity. However, the complex synthesis process of chemical methods and the pollution of chemical reag...

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Autores principales: Da Zhang, Yuanzheng Tang, Chuanqi Zhang, Qianpeng Dong, Wenming Song, Yan He
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:49cafe52acd346d593417be0c226e0622021-11-25T18:32:45ZOne-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries10.3390/nano111131382079-4991https://doaj.org/article/49cafe52acd346d593417be0c226e0622021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/3138https://doaj.org/toc/2079-4991Tin dioxide (SnO<sub>2</sub>)-based materials, as anode materials for lithium-ion batteries (LIBs), have been attracting growing research attention due to the high theoretical specific capacity. However, the complex synthesis process of chemical methods and the pollution of chemical reagents limit its commercialization. The new material synthesis method is of great significance for expanding the application of SnO<sub>2</sub>-based materials. In this study, the SnO<sub>2</sub>/carbon nanotube nanonests (SnO<sub>2</sub>/CNT NNs) composites are synthesized in one step by direct current (DC) arc-discharge plasma; compared with conventional methods, the plasma synthesis achieves a uniform load of SnO<sub>2</sub> nanoparticles on the surfaces of CNTs while constructing the CNTs conductive network. The SnO<sub>2</sub>/CNT NNs composites are applied in LIBs, it can be found that the nanonest-like CNT conductive structure provides adequate room for the volume expansion and also helps to transfer the electrons. Electrochemical measurements suggests that the SnO<sub>2</sub>/CNT NNscomposites achieve high capacity, and still have high electrochemical stability and coulombic efficiency under high current density, which proves the reliability of the synthesis method. This method is expected to be industrialized and also provides new ideas for the preparation of other nanocomposites.Da ZhangYuanzheng TangChuanqi ZhangQianpeng DongWenming SongYan HeMDPI AGarticletin oxidecarbon nanotubedirect current arc-discharge plasmalithium-ion batteriesanode materialsChemistryQD1-999ENNanomaterials, Vol 11, Iss 3138, p 3138 (2021)
institution DOAJ
collection DOAJ
language EN
topic tin oxide
carbon nanotube
direct current arc-discharge plasma
lithium-ion batteries
anode materials
Chemistry
QD1-999
spellingShingle tin oxide
carbon nanotube
direct current arc-discharge plasma
lithium-ion batteries
anode materials
Chemistry
QD1-999
Da Zhang
Yuanzheng Tang
Chuanqi Zhang
Qianpeng Dong
Wenming Song
Yan He
One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries
description Tin dioxide (SnO<sub>2</sub>)-based materials, as anode materials for lithium-ion batteries (LIBs), have been attracting growing research attention due to the high theoretical specific capacity. However, the complex synthesis process of chemical methods and the pollution of chemical reagents limit its commercialization. The new material synthesis method is of great significance for expanding the application of SnO<sub>2</sub>-based materials. In this study, the SnO<sub>2</sub>/carbon nanotube nanonests (SnO<sub>2</sub>/CNT NNs) composites are synthesized in one step by direct current (DC) arc-discharge plasma; compared with conventional methods, the plasma synthesis achieves a uniform load of SnO<sub>2</sub> nanoparticles on the surfaces of CNTs while constructing the CNTs conductive network. The SnO<sub>2</sub>/CNT NNs composites are applied in LIBs, it can be found that the nanonest-like CNT conductive structure provides adequate room for the volume expansion and also helps to transfer the electrons. Electrochemical measurements suggests that the SnO<sub>2</sub>/CNT NNscomposites achieve high capacity, and still have high electrochemical stability and coulombic efficiency under high current density, which proves the reliability of the synthesis method. This method is expected to be industrialized and also provides new ideas for the preparation of other nanocomposites.
format article
author Da Zhang
Yuanzheng Tang
Chuanqi Zhang
Qianpeng Dong
Wenming Song
Yan He
author_facet Da Zhang
Yuanzheng Tang
Chuanqi Zhang
Qianpeng Dong
Wenming Song
Yan He
author_sort Da Zhang
title One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries
title_short One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries
title_full One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries
title_fullStr One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries
title_full_unstemmed One-Step Synthesis of SnO<sub>2</sub>/Carbon Nanotube Nanonests Composites by Direct Current Arc-Discharge Plasma and Its Application in Lithium-Ion Batteries
title_sort one-step synthesis of sno<sub>2</sub>/carbon nanotube nanonests composites by direct current arc-discharge plasma and its application in lithium-ion batteries
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/49cafe52acd346d593417be0c226e062
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