Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation

Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluo...

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Autores principales:	Jie Luo, Qingxiang Cao, Xiaohui Cao, Xiaodan Zhao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4a0d9e72f5744e95a264d86f9555aaa5
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spelling	oai:doaj.org-article:4a0d9e72f5744e95a264d86f9555aaa52021-12-02T17:31:44ZSelenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation10.1038/s41467-018-02955-02041-1723https://doaj.org/article/4a0d9e72f5744e95a264d86f9555aaa52018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-02955-0https://doaj.org/toc/2041-1723Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation.Jie LuoQingxiang CaoXiaohui CaoXiaodan ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jie Luo Qingxiang Cao Xiaohui Cao Xiaodan Zhao Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
description	Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation.
format	article
author	Jie Luo Qingxiang Cao Xiaohui Cao Xiaodan Zhao
author_facet	Jie Luo Qingxiang Cao Xiaohui Cao Xiaodan Zhao
author_sort	Jie Luo
title	Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
title_short	Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
title_full	Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
title_fullStr	Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
title_full_unstemmed	Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
title_sort	selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/4a0d9e72f5744e95a264d86f9555aaa5
work_keys_str_mv	AT jieluo selenidecatalyzedenantioselectivesynthesisoftrifluoromethylthiolatedtetrahydronaphthalenesbymergingdesymmetrizationandtrifluoromethylthiolation AT qingxiangcao selenidecatalyzedenantioselectivesynthesisoftrifluoromethylthiolatedtetrahydronaphthalenesbymergingdesymmetrizationandtrifluoromethylthiolation AT xiaohuicao selenidecatalyzedenantioselectivesynthesisoftrifluoromethylthiolatedtetrahydronaphthalenesbymergingdesymmetrizationandtrifluoromethylthiolation AT xiaodanzhao selenidecatalyzedenantioselectivesynthesisoftrifluoromethylthiolatedtetrahydronaphthalenesbymergingdesymmetrizationandtrifluoromethylthiolation
_version_	1718380488453783552

Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation

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