Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry

Wastewater treatment in the cosmetic industry, which operates in batch mode, is a complex task due to the highly variable composition of the water to be treated. Among other parameters, n-heksan extractable material (HEM) and surfactants must comply with the specified limits. From theory, the advanc...

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Autores principales: Andreja Nemet, Miloš Bogataj, Zdravko Kravanja
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Lenguaje:EN
Publicado: AIDIC Servizi S.r.l. 2021
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Acceso en línea:https://doaj.org/article/4a21c1304d3f48ffa822082295e9b387
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spelling oai:doaj.org-article:4a21c1304d3f48ffa822082295e9b3872021-11-15T21:47:50ZOptimization of the Sequence of Wastewater Treatment in the Cosmetic Industry10.3303/CET21881192283-9216https://doaj.org/article/4a21c1304d3f48ffa822082295e9b3872021-11-01T00:00:00Zhttps://www.cetjournal.it/index.php/cet/article/view/11912https://doaj.org/toc/2283-9216Wastewater treatment in the cosmetic industry, which operates in batch mode, is a complex task due to the highly variable composition of the water to be treated. Among other parameters, n-heksan extractable material (HEM) and surfactants must comply with the specified limits. From theory, the advanced oxidation process (AOP) with a Fenton-like process is more suitable for surfactant degradation, while the coagulation/flocculation process (CFP) is more efficient for HEM removal. Determining the appropriate sequence of AOP treatment and CFP affects the quality of released water, the efficiency of each process step, and the consumption of required chemicals. The objective of this research was to optimize the treatment sequence, the time required for each treatment, and the amount of sludge from wastewater treatment. For this purpose, AOP treatment and CFP laboratory tests were performed for different groups of samples and samples with high HEM and/or surfactant content. Based on the efficiency of the laboratory tests and the assessed wastewater composition (from mass and concentration balances), an optimization model was developed. The optimization model enables optimization of the wastewater treatment plant (WWTP) by feeding each of the streams to either i) AOP treatment, ii) CFP treatment, iii) AOP treatment followed by CFP treatment, iv) CFP pretreatment followed by AOP and CFP, v) bypass (i.e. the wastewater stream is not treated but mixed with treated streams). The optimal solution can be determined by minimizing the total annual cost of treatment or/and maximizing removal of pollutants. An additional analysis was performed considering the dilution of wastewater with freshwater after the treatment process. The results show that this last proposal is more economical but leads to questionable environmental impacts.Andreja NemetMiloš BogatajZdravko KravanjaAIDIC Servizi S.r.l.articleChemical engineeringTP155-156Computer engineering. Computer hardwareTK7885-7895ENChemical Engineering Transactions, Vol 88 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
spellingShingle Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
Andreja Nemet
Miloš Bogataj
Zdravko Kravanja
Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry
description Wastewater treatment in the cosmetic industry, which operates in batch mode, is a complex task due to the highly variable composition of the water to be treated. Among other parameters, n-heksan extractable material (HEM) and surfactants must comply with the specified limits. From theory, the advanced oxidation process (AOP) with a Fenton-like process is more suitable for surfactant degradation, while the coagulation/flocculation process (CFP) is more efficient for HEM removal. Determining the appropriate sequence of AOP treatment and CFP affects the quality of released water, the efficiency of each process step, and the consumption of required chemicals. The objective of this research was to optimize the treatment sequence, the time required for each treatment, and the amount of sludge from wastewater treatment. For this purpose, AOP treatment and CFP laboratory tests were performed for different groups of samples and samples with high HEM and/or surfactant content. Based on the efficiency of the laboratory tests and the assessed wastewater composition (from mass and concentration balances), an optimization model was developed. The optimization model enables optimization of the wastewater treatment plant (WWTP) by feeding each of the streams to either i) AOP treatment, ii) CFP treatment, iii) AOP treatment followed by CFP treatment, iv) CFP pretreatment followed by AOP and CFP, v) bypass (i.e. the wastewater stream is not treated but mixed with treated streams). The optimal solution can be determined by minimizing the total annual cost of treatment or/and maximizing removal of pollutants. An additional analysis was performed considering the dilution of wastewater with freshwater after the treatment process. The results show that this last proposal is more economical but leads to questionable environmental impacts.
format article
author Andreja Nemet
Miloš Bogataj
Zdravko Kravanja
author_facet Andreja Nemet
Miloš Bogataj
Zdravko Kravanja
author_sort Andreja Nemet
title Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry
title_short Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry
title_full Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry
title_fullStr Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry
title_full_unstemmed Optimization of the Sequence of Wastewater Treatment in the Cosmetic Industry
title_sort optimization of the sequence of wastewater treatment in the cosmetic industry
publisher AIDIC Servizi S.r.l.
publishDate 2021
url https://doaj.org/article/4a21c1304d3f48ffa822082295e9b387
work_keys_str_mv AT andrejanemet optimizationofthesequenceofwastewatertreatmentinthecosmeticindustry
AT milosbogataj optimizationofthesequenceofwastewatertreatmentinthecosmeticindustry
AT zdravkokravanja optimizationofthesequenceofwastewatertreatmentinthecosmeticindustry
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