Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes

Cross coupling via the activation of two carbon-hydrogen bonds avoids the need for organometallic coupling partners and associated waste. Here, the authors report a radical process that allows selective coupling between alkynes and non-activated C(sp3)-H groups via a multimetallic catalytic system.

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Autores principales:	Shan Tang, Pan Wang, Haoran Li, Aiwen Lei
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4a3876d0a58d441380836d9bf61f808c
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spelling	oai:doaj.org-article:4a3876d0a58d441380836d9bf61f808c2021-12-02T14:38:34ZMultimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes10.1038/ncomms116762041-1723https://doaj.org/article/4a3876d0a58d441380836d9bf61f808c2016-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms11676https://doaj.org/toc/2041-1723Cross coupling via the activation of two carbon-hydrogen bonds avoids the need for organometallic coupling partners and associated waste. Here, the authors report a radical process that allows selective coupling between alkynes and non-activated C(sp3)-H groups via a multimetallic catalytic system.Shan TangPan WangHaoran LiAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shan Tang Pan Wang Haoran Li Aiwen Lei Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
description	Cross coupling via the activation of two carbon-hydrogen bonds avoids the need for organometallic coupling partners and associated waste. Here, the authors report a radical process that allows selective coupling between alkynes and non-activated C(sp3)-H groups via a multimetallic catalytic system.
format	article
author	Shan Tang Pan Wang Haoran Li Aiwen Lei
author_facet	Shan Tang Pan Wang Haoran Li Aiwen Lei
author_sort	Shan Tang
title	Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
title_short	Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
title_full	Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
title_fullStr	Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
title_full_unstemmed	Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
title_sort	multimetallic catalysed radical oxidative c(sp3)–h/c(sp)–h cross-coupling between unactivated alkanes and terminal alkynes
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/4a3876d0a58d441380836d9bf61f808c
work_keys_str_mv	AT shantang multimetalliccatalysedradicaloxidativecsp3hcsphcrosscouplingbetweenunactivatedalkanesandterminalalkynes AT panwang multimetalliccatalysedradicaloxidativecsp3hcsphcrosscouplingbetweenunactivatedalkanesandterminalalkynes AT haoranli multimetalliccatalysedradicaloxidativecsp3hcsphcrosscouplingbetweenunactivatedalkanesandterminalalkynes AT aiwenlei multimetalliccatalysedradicaloxidativecsp3hcsphcrosscouplingbetweenunactivatedalkanesandterminalalkynes
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Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes

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