Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes

Cross coupling via the activation of two carbon-hydrogen bonds avoids the need for organometallic coupling partners and associated waste. Here, the authors report a radical process that allows selective coupling between alkynes and non-activated C(sp3)-H groups via a multimetallic catalytic system.

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Auteurs principaux: Shan Tang, Pan Wang, Haoran Li, Aiwen Lei
Format: article
Langue:EN
Publié: Nature Portfolio 2016
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Accès en ligne:https://doaj.org/article/4a3876d0a58d441380836d9bf61f808c
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