Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
In the title compound, C14H7Cl4FN2, the dihedral angle between the 4-fluorophenyl ring and the 2,4-dichlorophenyl ring is 46.03 (19)°. In the crystal, the molecules are linked by C—H...N interactions along the a-axis direction, forming a C(6) chain. The molecules are further connected by C—Cl...π in...
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| Autores principales: | , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
International Union of Crystallography
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/4ae45dcb36934073a7cfce18e8b0be07 |
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| Sumario: | In the title compound, C14H7Cl4FN2, the dihedral angle between the 4-fluorophenyl ring and the 2,4-dichlorophenyl ring is 46.03 (19)°. In the crystal, the molecules are linked by C—H...N interactions along the a-axis direction, forming a C(6) chain. The molecules are further connected by C—Cl...π interactions and face-to-face π–π stacking interactions, forming ribbons along the a-axis direction. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from Cl...H/H...Cl (35.1%), H...H (10.6%), C...C (9.7%), Cl...Cl (9.4%) and C...H/H...C (9.2%) interactions. |
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