Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene

In the title compound, C14H7Cl4FN2, the dihedral angle between the 4-fluorophenyl ring and the 2,4-dichlorophenyl ring is 46.03 (19)°. In the crystal, the molecules are linked by C—H...N interactions along the a-axis direction, forming a C(6) chain. The molecules are further connected by C—Cl...π in...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Namiq Q. Shikhaliyev, Kadiriye Özkaraca, Mehmet Akkurt, Xanim N. Bagirova, Gulnar T. Suleymanova, Mirjalil S. Abdulov, Sixberth Mlowe
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	crystal structure short inter hl...hl contact c—cl...π interactions face-to-face π–π stacking interactions hirshfeld surface analysis Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/4ae45dcb36934073a7cfce18e8b0be07
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:4ae45dcb36934073a7cfce18e8b0be07
record_format	dspace
spelling	oai:doaj.org-article:4ae45dcb36934073a7cfce18e8b0be072021-11-12T11:16:09ZCrystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene2056-989010.1107/S2056989021010756https://doaj.org/article/4ae45dcb36934073a7cfce18e8b0be072021-11-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2056989021010756https://doaj.org/toc/2056-9890In the title compound, C14H7Cl4FN2, the dihedral angle between the 4-fluorophenyl ring and the 2,4-dichlorophenyl ring is 46.03 (19)°. In the crystal, the molecules are linked by C—H...N interactions along the a-axis direction, forming a C(6) chain. The molecules are further connected by C—Cl...π interactions and face-to-face π–π stacking interactions, forming ribbons along the a-axis direction. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from Cl...H/H...Cl (35.1%), H...H (10.6%), C...C (9.7%), Cl...Cl (9.4%) and C...H/H...C (9.2%) interactions.Namiq Q. ShikhaliyevKadiriye ÖzkaracaMehmet AkkurtXanim N. BagirovaGulnar T. SuleymanovaMirjalil S. AbdulovSixberth MloweInternational Union of Crystallographyarticlecrystal structureshort inter hl...hl contactc—cl...π interactionsface-to-face π–π stacking interactionshirshfeld surface analysisChemistryQD1-999ENActa Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 11, Pp 1158-1163 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal structure short inter hl...hl contact c—cl...π interactions face-to-face π–π stacking interactions hirshfeld surface analysis Chemistry QD1-999
spellingShingle	crystal structure short inter hl...hl contact c—cl...π interactions face-to-face π–π stacking interactions hirshfeld surface analysis Chemistry QD1-999 Namiq Q. Shikhaliyev Kadiriye Özkaraca Mehmet Akkurt Xanim N. Bagirova Gulnar T. Suleymanova Mirjalil S. Abdulov Sixberth Mlowe Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
description	In the title compound, C14H7Cl4FN2, the dihedral angle between the 4-fluorophenyl ring and the 2,4-dichlorophenyl ring is 46.03 (19)°. In the crystal, the molecules are linked by C—H...N interactions along the a-axis direction, forming a C(6) chain. The molecules are further connected by C—Cl...π interactions and face-to-face π–π stacking interactions, forming ribbons along the a-axis direction. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from Cl...H/H...Cl (35.1%), H...H (10.6%), C...C (9.7%), Cl...Cl (9.4%) and C...H/H...C (9.2%) interactions.
format	article
author	Namiq Q. Shikhaliyev Kadiriye Özkaraca Mehmet Akkurt Xanim N. Bagirova Gulnar T. Suleymanova Mirjalil S. Abdulov Sixberth Mlowe
author_facet	Namiq Q. Shikhaliyev Kadiriye Özkaraca Mehmet Akkurt Xanim N. Bagirova Gulnar T. Suleymanova Mirjalil S. Abdulov Sixberth Mlowe
author_sort	Namiq Q. Shikhaliyev
title	Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
title_short	Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
title_full	Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
title_fullStr	Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
title_full_unstemmed	Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
title_sort	crystal structure and hirshfeld surface analysis of (e)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/4ae45dcb36934073a7cfce18e8b0be07
work_keys_str_mv	AT namiqqshikhaliyev crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene AT kadiriyeozkaraca crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene AT mehmetakkurt crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene AT xanimnbagirova crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene AT gulnartsuleymanova crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene AT mirjalilsabdulov crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene AT sixberthmlowe crystalstructureandhirshfeldsurfaceanalysisofe122dichloro14fluorophenylethenyl224dichlorophenyldiazene
_version_	1718430614610247680

Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]-2-(2,4-dichlorophenyl)diazene

Ejemplares similares