Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea

Although various geochemical and geophysical investigations have already indicated a great resource potential in the Xisha area of the South China Sea, the origin of organic matter and molecular evidence for tracing the migration of hydrocarbons from deep petroleum reservoirs are still lacking. In t...

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Autores principales: Yan Li, Qian-Zhi Zhou, Xiang-Po Xu, Yun-Xin Fang, Jin-Zhong Liu, Jiang-Hai Wang
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/4b0f6fb5c3ef437eb2a736580ee6a6ca
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spelling oai:doaj.org-article:4b0f6fb5c3ef437eb2a736580ee6a6ca2021-11-25T18:27:24ZSource Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea10.3390/molecules262268081420-3049https://doaj.org/article/4b0f6fb5c3ef437eb2a736580ee6a6ca2021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6808https://doaj.org/toc/1420-3049Although various geochemical and geophysical investigations have already indicated a great resource potential in the Xisha area of the South China Sea, the origin of organic matter and molecular evidence for tracing the migration of hydrocarbons from deep petroleum reservoirs are still lacking. In this study, systematic organic geochemical analyses, including bulk organic matter parameters and lipid biomarkers were performed for deep sediments from two cores. The C/N ratios and δ<sup>13</sup>C and δ<sup>15</sup>N values of organic matter in most of the samples, together with the maxima of short-chain <i>n</i>-alkanoic acids and mid-chain <i>n</i>-alkanols, high abundances of monounsaturated fatty acids C<sub>18:1ω9</sub> and C<sub>22:1ω13</sub>, jointly indicate the dominance of marine organic matter. <i>n</i>-Alkanes in sediments from core GMGS4-XH-W06B are characterized by small unresolved complex mixture (UCMs) humps, high odd/even predominance (OEP) and carbon preference index (CPI) values, clearly exhibiting characteristics of modern sediments. However, the sediments for core GMGS4-XH-W03B are featured with big UCMs, associated with OEP and CPI values around 1.0, showing signatures of petroleum hydrocarbons from high maturity sources. Considering the geologic background, the biomarker signatures are solid evidence for indicating the existence of underlying petroleum reservoirs, and may provide the valuable information for assessing the hydrocarbon resources in the Xisha area.Yan LiQian-Zhi ZhouXiang-Po XuYun-Xin FangJin-Zhong LiuJiang-Hai WangMDPI AGarticlesource indicationsedimentary organic matterbiomarkerspetroleum hydrocarbonsXisha areaSouth China SeaOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6808, p 6808 (2021)
institution DOAJ
collection DOAJ
language EN
topic source indication
sedimentary organic matter
biomarkers
petroleum hydrocarbons
Xisha area
South China Sea
Organic chemistry
QD241-441
spellingShingle source indication
sedimentary organic matter
biomarkers
petroleum hydrocarbons
Xisha area
South China Sea
Organic chemistry
QD241-441
Yan Li
Qian-Zhi Zhou
Xiang-Po Xu
Yun-Xin Fang
Jin-Zhong Liu
Jiang-Hai Wang
Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea
description Although various geochemical and geophysical investigations have already indicated a great resource potential in the Xisha area of the South China Sea, the origin of organic matter and molecular evidence for tracing the migration of hydrocarbons from deep petroleum reservoirs are still lacking. In this study, systematic organic geochemical analyses, including bulk organic matter parameters and lipid biomarkers were performed for deep sediments from two cores. The C/N ratios and δ<sup>13</sup>C and δ<sup>15</sup>N values of organic matter in most of the samples, together with the maxima of short-chain <i>n</i>-alkanoic acids and mid-chain <i>n</i>-alkanols, high abundances of monounsaturated fatty acids C<sub>18:1ω9</sub> and C<sub>22:1ω13</sub>, jointly indicate the dominance of marine organic matter. <i>n</i>-Alkanes in sediments from core GMGS4-XH-W06B are characterized by small unresolved complex mixture (UCMs) humps, high odd/even predominance (OEP) and carbon preference index (CPI) values, clearly exhibiting characteristics of modern sediments. However, the sediments for core GMGS4-XH-W03B are featured with big UCMs, associated with OEP and CPI values around 1.0, showing signatures of petroleum hydrocarbons from high maturity sources. Considering the geologic background, the biomarker signatures are solid evidence for indicating the existence of underlying petroleum reservoirs, and may provide the valuable information for assessing the hydrocarbon resources in the Xisha area.
format article
author Yan Li
Qian-Zhi Zhou
Xiang-Po Xu
Yun-Xin Fang
Jin-Zhong Liu
Jiang-Hai Wang
author_facet Yan Li
Qian-Zhi Zhou
Xiang-Po Xu
Yun-Xin Fang
Jin-Zhong Liu
Jiang-Hai Wang
author_sort Yan Li
title Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea
title_short Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea
title_full Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea
title_fullStr Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea
title_full_unstemmed Source Indication and Geochemical Significance of Sedimentary Organic Matters from the Xisha Area, the South China Sea
title_sort source indication and geochemical significance of sedimentary organic matters from the xisha area, the south china sea
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/4b0f6fb5c3ef437eb2a736580ee6a6ca
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AT qianzhizhou sourceindicationandgeochemicalsignificanceofsedimentaryorganicmattersfromthexishaareathesouthchinasea
AT xiangpoxu sourceindicationandgeochemicalsignificanceofsedimentaryorganicmattersfromthexishaareathesouthchinasea
AT yunxinfang sourceindicationandgeochemicalsignificanceofsedimentaryorganicmattersfromthexishaareathesouthchinasea
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