Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles

Amides are versatile synthetic building blocks, however the general stability of the amide bond makes its selective transformation challenging. Here, the authors report a chemodivergent transformation of primary, secondary and tertiary amides by using 1,1-diborylalkanes as pro-nucleophiles.

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Autores principales:	Wei Sun, Lu Wang, Yue Hu, Xudong Wu, Chungu Xia, Chao Liu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4b22bfab9b2144148ecc7d4a1a054407
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spelling	oai:doaj.org-article:4b22bfab9b2144148ecc7d4a1a0544072021-12-02T17:40:00ZChemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles10.1038/s41467-020-16948-52041-1723https://doaj.org/article/4b22bfab9b2144148ecc7d4a1a0544072020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16948-5https://doaj.org/toc/2041-1723Amides are versatile synthetic building blocks, however the general stability of the amide bond makes its selective transformation challenging. Here, the authors report a chemodivergent transformation of primary, secondary and tertiary amides by using 1,1-diborylalkanes as pro-nucleophiles.Wei SunLu WangYue HuXudong WuChungu XiaChao LiuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Wei Sun Lu Wang Yue Hu Xudong Wu Chungu Xia Chao Liu Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
description	Amides are versatile synthetic building blocks, however the general stability of the amide bond makes its selective transformation challenging. Here, the authors report a chemodivergent transformation of primary, secondary and tertiary amides by using 1,1-diborylalkanes as pro-nucleophiles.
format	article
author	Wei Sun Lu Wang Yue Hu Xudong Wu Chungu Xia Chao Liu
author_facet	Wei Sun Lu Wang Yue Hu Xudong Wu Chungu Xia Chao Liu
author_sort	Wei Sun
title	Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
title_short	Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
title_full	Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
title_fullStr	Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
title_full_unstemmed	Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
title_sort	chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/4b22bfab9b2144148ecc7d4a1a054407
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Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles

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