Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles

Amides are versatile synthetic building blocks, however the general stability of the amide bond makes its selective transformation challenging. Here, the authors report a chemodivergent transformation of primary, secondary and tertiary amides by using 1,1-diborylalkanes as pro-nucleophiles.

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Auteurs principaux: Wei Sun, Lu Wang, Yue Hu, Xudong Wu, Chungu Xia, Chao Liu
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/4b22bfab9b2144148ecc7d4a1a054407
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