Pyrite/H2O2/hydroxylamine system for efficient decolorization of rhodamine B
To improve the efficiency of the Fe(II)/Fe(III) cycle and continuous reactivity of pyrite, a pyrite/H2O2/hydroxylamine (HA) system was proposed to treat rhodamine B (RhB). The results showed that near-complete decolorization and 52.8% mineralization 50 mg L−1 RhB were achieved under its optimum cond...
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
IWA Publishing
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/4b2812df96e04324bda8a1b3c52fede0 |
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| Sumario: | To improve the efficiency of the Fe(II)/Fe(III) cycle and continuous reactivity of pyrite, a pyrite/H2O2/hydroxylamine (HA) system was proposed to treat rhodamine B (RhB). The results showed that near-complete decolorization and 52.8% mineralization 50 mg L−1 RhB were achieved under its optimum conditions: HA 0.8 mM, H2O2 1.6 mM, pyrite 0.4 g L−1, and initial pH 4.0. The degradation reaction was dominated by an •OH radical produced by the reaction of Fe2+ with H2O2 in solution. HA primarily had two roles: in solution, HA could accelerate the Fe(II)/Fe(III) cycle through its strong reducibility to enhance RhB decolorization; on the pyrite surface, HA could improve the continuous reactivity of pyrite by inhibiting the oxidation of pyrite. In addition, the dosing manner of HA had a significant effect on RhB decolorization. In addition, the high decolorization and mineralization efficiency of other dye pollutants suggested that the pyrite/H2O2/HA system might be widely used in textile wastewater treatment. HIGHLIGHTS
A pyrite/H2O2/HA system was proposed for efficient RhB decolorization in a wide-range pH of 3.0–10.0.;
HA could not only promote the Fe(II)/Fe(III) cycle to enhance the decolorization of RhB, but also improve the continuous reactivity of pyrite.;
The dosing manner of HA had a notable effect on RhB decolorization.;
Complete decolorization and high mineralization of other dye pollutants were achieved by the proposed system.; |
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