Iridium-catalyzed reductive Ugi-type reactions of tertiary amides

Chemical transformation of amides is normally occurring under harsh conditions. Here, the authors report a mild iridium-catalyzed reductive Ugi-type coupling of tertiary amides, isocyanides and (thio)acetic acid or trimethylsilyl azide to give homologous, bioactive amine products.

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Auteurs principaux: Lan-Gui Xie, Darren J. Dixon
Format: article
Langue:EN
Publié: Nature Portfolio 2018
Sujets:
Q
Accès en ligne:https://doaj.org/article/4b7210f119d94a6dbf78675cb6192eb4
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