Crystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenases

Crystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenases

[FeFe]-hydrogenases catalyze H2-evolution and -oxidation at very high turnover-rates. Here the authors provide experimental evidence for the proposed proton-transfer (PT) pathway by kinetically, spectroscopically, and crystallographically characterizing eleven mutants from the two [FeFe]-hydrogenase...

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Autores principales: Jifu Duan, Moritz Senger, Julian Esselborn, Vera Engelbrecht, Florian Wittkamp, Ulf-Peter Apfel, Eckhard Hofmann, Sven T. Stripp, Thomas Happe, Martin Winkler
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/4bada01f9d834987b23d9982e7b4807b
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