Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions

The mechanism by which C-C bonds form during Fischer-Tropsch synthesis remains debated while spectroscopic identification of reaction intermediates remains scarce. Here, the authors identify alkylidynes as reactive intermediates for C-C bond formation on cobalt terrace sites and moreover show that t...

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Autores principales:	C. J. (Kees-Jan) Weststrate, Devyani Sharma, Daniel Garcia Rodriguez, Michael A. Gleeson, Hans O. A. Fredriksson, J. W. (Hans) Niemantsverdriet
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4be01cb5d04d4918836c0cfd24148668
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spelling	oai:doaj.org-article:4be01cb5d04d4918836c0cfd241486682021-12-02T15:39:16ZMechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions10.1038/s41467-020-14613-52041-1723https://doaj.org/article/4be01cb5d04d4918836c0cfd241486682020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14613-5https://doaj.org/toc/2041-1723The mechanism by which C-C bonds form during Fischer-Tropsch synthesis remains debated while spectroscopic identification of reaction intermediates remains scarce. Here, the authors identify alkylidynes as reactive intermediates for C-C bond formation on cobalt terrace sites and moreover show that these intermediates are stabilized by the high surface coverage typical for Fischer-Tropsch synthesis.C. J. (Kees-Jan) WeststrateDevyani SharmaDaniel Garcia RodriguezMichael A. GleesonHans O. A. FredrikssonJ. W. (Hans) NiemantsverdrietNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q C. J. (Kees-Jan) Weststrate Devyani Sharma Daniel Garcia Rodriguez Michael A. Gleeson Hans O. A. Fredriksson J. W. (Hans) Niemantsverdriet Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
description	The mechanism by which C-C bonds form during Fischer-Tropsch synthesis remains debated while spectroscopic identification of reaction intermediates remains scarce. Here, the authors identify alkylidynes as reactive intermediates for C-C bond formation on cobalt terrace sites and moreover show that these intermediates are stabilized by the high surface coverage typical for Fischer-Tropsch synthesis.
format	article
author	C. J. (Kees-Jan) Weststrate Devyani Sharma Daniel Garcia Rodriguez Michael A. Gleeson Hans O. A. Fredriksson J. W. (Hans) Niemantsverdriet
author_facet	C. J. (Kees-Jan) Weststrate Devyani Sharma Daniel Garcia Rodriguez Michael A. Gleeson Hans O. A. Fredriksson J. W. (Hans) Niemantsverdriet
author_sort	C. J. (Kees-Jan) Weststrate
title	Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
title_short	Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
title_full	Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
title_fullStr	Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
title_full_unstemmed	Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
title_sort	mechanistic insight into carbon-carbon bond formation on cobalt under simulated fischer-tropsch synthesis conditions
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/4be01cb5d04d4918836c0cfd24148668
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Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions

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