Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems

Response surface methodology accompanied by Central Composite Design (CCD) was employed in this study to optimize Alternanthera spp-based phytoremediation process for the removal of acetaminophen and methylparaben individually. Two operational variables, including concentration (A) (20, 60,100 mg/L)...

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Autores principales: Zahraa Hasan Mutar, Ahmed A. Mohammed, Israa Abdulwahab Al-Baldawi
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Publicado: Polish Society of Ecological Engineering (PTIE) 2022
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spelling oai:doaj.org-article:4c0c83d8f6eb4e669c696e52906b25582021-12-01T13:20:42ZOptimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems2299-899310.12911/22998993/143934https://doaj.org/article/4c0c83d8f6eb4e669c696e52906b25582022-01-01T00:00:00Zhttp://www.jeeng.net/Optimization-of-Acetaminophen-and-Methylparaben-Removal-within-Subsurface-Batch-Constructed,143934,0,2.htmlhttps://doaj.org/toc/2299-8993Response surface methodology accompanied by Central Composite Design (CCD) was employed in this study to optimize Alternanthera spp-based phytoremediation process for the removal of acetaminophen and methylparaben individually. Two operational variables, including concentration (A) (20, 60,100 mg/L) and sampling time (B) (7, 14, 21, and 35 days) were involved in the study for removal efficiency (Y) as response. CCD had required a total of 18 experiments for each compound. Analysis of variance (ANOVA) was conducted to verify the adequacy of the proposed mathematical models and revealed good agreement with the experimental data. The observed R2 values (0.9732 and 0.9870), adjusted R2 (0.9620 and 0.9816) and predicted R2 (0.9383 and 0.9721) for AC and MP, respectively, indicated that the developed models were significant at the 95% probability level. Concentration factor was found to be not significant in the mathematical models; in contrast, sampling time was found to be of a crucial role. The removal of AC and MP were 89.23% and 64.48% at optimum conditions of A = 100 mg/L and B = 35 days respectively. Validation test confirmed the predicted results attained by Central Composite Design, as the removals achieved at the optimum conditions was 91.04% and 59.17% for AC and MP, respectively, which were in good agreement with the results proposed by the theoretical design.Zahraa Hasan MutarAhmed A. MohammedIsraa Abdulwahab Al-BaldawiPolish Society of Ecological Engineering (PTIE)articleppcpsphytoremediationornamental plantcentral composite designconstructed wetlandsEnvironmental technology. Sanitary engineeringTD1-1066Environmental sciencesGE1-350ENJournal of Ecological Engineering, Vol 23, Iss 1, Pp 228-239 (2022)
institution DOAJ
collection DOAJ
language EN
topic ppcps
phytoremediation
ornamental plant
central composite design
constructed wetlands
Environmental technology. Sanitary engineering
TD1-1066
Environmental sciences
GE1-350
spellingShingle ppcps
phytoremediation
ornamental plant
central composite design
constructed wetlands
Environmental technology. Sanitary engineering
TD1-1066
Environmental sciences
GE1-350
Zahraa Hasan Mutar
Ahmed A. Mohammed
Israa Abdulwahab Al-Baldawi
Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems
description Response surface methodology accompanied by Central Composite Design (CCD) was employed in this study to optimize Alternanthera spp-based phytoremediation process for the removal of acetaminophen and methylparaben individually. Two operational variables, including concentration (A) (20, 60,100 mg/L) and sampling time (B) (7, 14, 21, and 35 days) were involved in the study for removal efficiency (Y) as response. CCD had required a total of 18 experiments for each compound. Analysis of variance (ANOVA) was conducted to verify the adequacy of the proposed mathematical models and revealed good agreement with the experimental data. The observed R2 values (0.9732 and 0.9870), adjusted R2 (0.9620 and 0.9816) and predicted R2 (0.9383 and 0.9721) for AC and MP, respectively, indicated that the developed models were significant at the 95% probability level. Concentration factor was found to be not significant in the mathematical models; in contrast, sampling time was found to be of a crucial role. The removal of AC and MP were 89.23% and 64.48% at optimum conditions of A = 100 mg/L and B = 35 days respectively. Validation test confirmed the predicted results attained by Central Composite Design, as the removals achieved at the optimum conditions was 91.04% and 59.17% for AC and MP, respectively, which were in good agreement with the results proposed by the theoretical design.
format article
author Zahraa Hasan Mutar
Ahmed A. Mohammed
Israa Abdulwahab Al-Baldawi
author_facet Zahraa Hasan Mutar
Ahmed A. Mohammed
Israa Abdulwahab Al-Baldawi
author_sort Zahraa Hasan Mutar
title Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems
title_short Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems
title_full Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems
title_fullStr Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems
title_full_unstemmed Optimization of Acetaminophen and Methylparaben Removal within Subsurface Batch Constructed Wetland Systems
title_sort optimization of acetaminophen and methylparaben removal within subsurface batch constructed wetland systems
publisher Polish Society of Ecological Engineering (PTIE)
publishDate 2022
url https://doaj.org/article/4c0c83d8f6eb4e669c696e52906b2558
work_keys_str_mv AT zahraahasanmutar optimizationofacetaminophenandmethylparabenremovalwithinsubsurfacebatchconstructedwetlandsystems
AT ahmedamohammed optimizationofacetaminophenandmethylparabenremovalwithinsubsurfacebatchconstructedwetlandsystems
AT israaabdulwahabalbaldawi optimizationofacetaminophenandmethylparabenremovalwithinsubsurfacebatchconstructedwetlandsystems
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