Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes

Asymmetric intermolecular hydroamination of alkenes is a challenging process, potentially leading to useful chiral amines. Here, the authors report unsymmetric NNN tridentate ligands promoting the cobalt-catalyzed radical hydroamination of alkenes via hydrogen atom transfer, also in an asymmetric fa...

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Autores principales: Xuzhong Shen, Xu Chen, Jieping Chen, Yufeng Sun, Zhaoyang Cheng, Zhan Lu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/4c165240e7d542f98b4a262c5a06a45b
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spelling oai:doaj.org-article:4c165240e7d542f98b4a262c5a06a45b2021-12-02T14:42:56ZLigand-promoted cobalt-catalyzed radical hydroamination of alkenes10.1038/s41467-020-14459-x2041-1723https://doaj.org/article/4c165240e7d542f98b4a262c5a06a45b2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14459-xhttps://doaj.org/toc/2041-1723Asymmetric intermolecular hydroamination of alkenes is a challenging process, potentially leading to useful chiral amines. Here, the authors report unsymmetric NNN tridentate ligands promoting the cobalt-catalyzed radical hydroamination of alkenes via hydrogen atom transfer, also in an asymmetric fashion.Xuzhong ShenXu ChenJieping ChenYufeng SunZhaoyang ChengZhan LuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xuzhong Shen
Xu Chen
Jieping Chen
Yufeng Sun
Zhaoyang Cheng
Zhan Lu
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
description Asymmetric intermolecular hydroamination of alkenes is a challenging process, potentially leading to useful chiral amines. Here, the authors report unsymmetric NNN tridentate ligands promoting the cobalt-catalyzed radical hydroamination of alkenes via hydrogen atom transfer, also in an asymmetric fashion.
format article
author Xuzhong Shen
Xu Chen
Jieping Chen
Yufeng Sun
Zhaoyang Cheng
Zhan Lu
author_facet Xuzhong Shen
Xu Chen
Jieping Chen
Yufeng Sun
Zhaoyang Cheng
Zhan Lu
author_sort Xuzhong Shen
title Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
title_short Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
title_full Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
title_fullStr Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
title_full_unstemmed Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
title_sort ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/4c165240e7d542f98b4a262c5a06a45b
work_keys_str_mv AT xuzhongshen ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes
AT xuchen ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes
AT jiepingchen ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes
AT yufengsun ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes
AT zhaoyangcheng ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes
AT zhanlu ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes
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