Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes
Asymmetric intermolecular hydroamination of alkenes is a challenging process, potentially leading to useful chiral amines. Here, the authors report unsymmetric NNN tridentate ligands promoting the cobalt-catalyzed radical hydroamination of alkenes via hydrogen atom transfer, also in an asymmetric fa...
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2020
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oai:doaj.org-article:4c165240e7d542f98b4a262c5a06a45b2021-12-02T14:42:56ZLigand-promoted cobalt-catalyzed radical hydroamination of alkenes10.1038/s41467-020-14459-x2041-1723https://doaj.org/article/4c165240e7d542f98b4a262c5a06a45b2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14459-xhttps://doaj.org/toc/2041-1723Asymmetric intermolecular hydroamination of alkenes is a challenging process, potentially leading to useful chiral amines. Here, the authors report unsymmetric NNN tridentate ligands promoting the cobalt-catalyzed radical hydroamination of alkenes via hydrogen atom transfer, also in an asymmetric fashion.Xuzhong ShenXu ChenJieping ChenYufeng SunZhaoyang ChengZhan LuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020) |
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Science Q Xuzhong Shen Xu Chen Jieping Chen Yufeng Sun Zhaoyang Cheng Zhan Lu Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
description |
Asymmetric intermolecular hydroamination of alkenes is a challenging process, potentially leading to useful chiral amines. Here, the authors report unsymmetric NNN tridentate ligands promoting the cobalt-catalyzed radical hydroamination of alkenes via hydrogen atom transfer, also in an asymmetric fashion. |
format |
article |
author |
Xuzhong Shen Xu Chen Jieping Chen Yufeng Sun Zhaoyang Cheng Zhan Lu |
author_facet |
Xuzhong Shen Xu Chen Jieping Chen Yufeng Sun Zhaoyang Cheng Zhan Lu |
author_sort |
Xuzhong Shen |
title |
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
title_short |
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
title_full |
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
title_fullStr |
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
title_full_unstemmed |
Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
title_sort |
ligand-promoted cobalt-catalyzed radical hydroamination of alkenes |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/4c165240e7d542f98b4a262c5a06a45b |
work_keys_str_mv |
AT xuzhongshen ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes AT xuchen ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes AT jiepingchen ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes AT yufengsun ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes AT zhaoyangcheng ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes AT zhanlu ligandpromotedcobaltcatalyzedradicalhydroaminationofalkenes |
_version_ |
1718389565724557312 |