Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands

The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, inc...

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Autores principales: Zhang Lu-Lin, Tang Shi-Li, Li De-Jun, Cheng Yuan-Zheng, Zhang Li-Ping
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Publicado: De Gruyter 2021
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spelling oai:doaj.org-article:4cc75cb05d9040e485ec3b194d28e96b2021-12-05T14:10:55ZSynthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands0792-12412191-021910.1515/mgmc-2021-0019https://doaj.org/article/4cc75cb05d9040e485ec3b194d28e96b2021-06-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0019https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture.Zhang Lu-LinTang Shi-LiLi De-JunCheng Yuan-ZhengZhang Li-PingDe Gruyterarticlelead(ii)1,10-phenanthroline4-nitrobenzoateacetatecrystal structureChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 157-164 (2021)
institution DOAJ
collection DOAJ
language EN
topic lead(ii)
1,10-phenanthroline
4-nitrobenzoate
acetate
crystal structure
Chemistry
QD1-999
spellingShingle lead(ii)
1,10-phenanthroline
4-nitrobenzoate
acetate
crystal structure
Chemistry
QD1-999
Zhang Lu-Lin
Tang Shi-Li
Li De-Jun
Cheng Yuan-Zheng
Zhang Li-Ping
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
description The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture.
format article
author Zhang Lu-Lin
Tang Shi-Li
Li De-Jun
Cheng Yuan-Zheng
Zhang Li-Ping
author_facet Zhang Lu-Lin
Tang Shi-Li
Li De-Jun
Cheng Yuan-Zheng
Zhang Li-Ping
author_sort Zhang Lu-Lin
title Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
title_short Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
title_full Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
title_fullStr Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
title_full_unstemmed Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
title_sort synthesis and crystal structure of one new pb(ii) complex constructed by 1,10-phenanthroline and two carboxylate ligands
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/4cc75cb05d9040e485ec3b194d28e96b
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AT tangshili synthesisandcrystalstructureofonenewpbiicomplexconstructedby110phenanthrolineandtwocarboxylateligands
AT lidejun synthesisandcrystalstructureofonenewpbiicomplexconstructedby110phenanthrolineandtwocarboxylateligands
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