Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, inc...
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oai:doaj.org-article:4cc75cb05d9040e485ec3b194d28e96b2021-12-05T14:10:55ZSynthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands0792-12412191-021910.1515/mgmc-2021-0019https://doaj.org/article/4cc75cb05d9040e485ec3b194d28e96b2021-06-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0019https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture.Zhang Lu-LinTang Shi-LiLi De-JunCheng Yuan-ZhengZhang Li-PingDe Gruyterarticlelead(ii)1,10-phenanthroline4-nitrobenzoateacetatecrystal structureChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 157-164 (2021) |
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lead(ii) 1,10-phenanthroline 4-nitrobenzoate acetate crystal structure Chemistry QD1-999 |
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lead(ii) 1,10-phenanthroline 4-nitrobenzoate acetate crystal structure Chemistry QD1-999 Zhang Lu-Lin Tang Shi-Li Li De-Jun Cheng Yuan-Zheng Zhang Li-Ping Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
description |
The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture. |
format |
article |
author |
Zhang Lu-Lin Tang Shi-Li Li De-Jun Cheng Yuan-Zheng Zhang Li-Ping |
author_facet |
Zhang Lu-Lin Tang Shi-Li Li De-Jun Cheng Yuan-Zheng Zhang Li-Ping |
author_sort |
Zhang Lu-Lin |
title |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
title_short |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
title_full |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
title_fullStr |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
title_full_unstemmed |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
title_sort |
synthesis and crystal structure of one new pb(ii) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/4cc75cb05d9040e485ec3b194d28e96b |
work_keys_str_mv |
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