Low Friction Property of Boron Doped DLC under Engine Oil

DLC films are of significant interest for automobile parts, because they possess the potential to improve the friction property under oil lubricated conditions. In order to obtain further low friction, we focused on the combination of boron doped DLC (B-DLC) and the Mo-trimer as a lubricating oil ad...

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Autores principales: Hiroyuki Mori, Mamoru Tohyama, Masaru Okuyama, Toshihide Ohmori, Naoya Ikeda, Keiji Hayashi
Formato: article
Lenguaje:EN
Publicado: Japanese Society of Tribologists 2017
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Acceso en línea:https://doaj.org/article/4cc7af21cab44a089ebd92d0ec8e1028
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spelling oai:doaj.org-article:4cc7af21cab44a089ebd92d0ec8e10282021-11-05T09:20:26ZLow Friction Property of Boron Doped DLC under Engine Oil1881-219810.2474/trol.12.135https://doaj.org/article/4cc7af21cab44a089ebd92d0ec8e10282017-07-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/trol/12/3/12_135/_pdf/-char/enhttps://doaj.org/toc/1881-2198DLC films are of significant interest for automobile parts, because they possess the potential to improve the friction property under oil lubricated conditions. In order to obtain further low friction, we focused on the combination of boron doped DLC (B-DLC) and the Mo-trimer as a lubricating oil additive, and the influence of the boron concentration on the friction property of the B-DLC films was evaluated by a block on ring type test. Compared to DLC films without boron, the B-DLC films exhibited an extremely low friction coefficient below 0.03 ranging from 2 to 12 at% in boron concentration under the lubricating condition using the engine oil containing the Mo-trimer. It was found that the surface roughness of the B-DLC films rubbed in the oil containing the Mo-trimer became particularly smooth below 2 nm measured by an atomic force microscope. On the wear surface of the B-DLC films, Mo3S7- derived from the Mo-trimer was selectively confirmed as having a uniform distribution by time-of-flight secondary ion mass spectrometry. Based on the obtained results of surface measurements and analyses, it was suggested that the B-DLC films exhibited a low friction property primarily caused by the nano-scale smooth surface, disturbing the adsorption of the other additives and the transfer reaction products from the counter parts by forming a selective adsorbed Mo-trimer film on the B-DLC surface.Hiroyuki MoriMamoru TohyamaMasaru OkuyamaToshihide OhmoriNaoya IkedaKeiji HayashiJapanese Society of Tribologistsarticledlcboronlow frictionengine oiladditivemo-trimerPhysicsQC1-999Engineering (General). Civil engineering (General)TA1-2040Mechanical engineering and machineryTJ1-1570ChemistryQD1-999ENTribology Online, Vol 12, Iss 3, Pp 135-140 (2017)
institution DOAJ
collection DOAJ
language EN
topic dlc
boron
low friction
engine oil
additive
mo-trimer
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
spellingShingle dlc
boron
low friction
engine oil
additive
mo-trimer
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
Hiroyuki Mori
Mamoru Tohyama
Masaru Okuyama
Toshihide Ohmori
Naoya Ikeda
Keiji Hayashi
Low Friction Property of Boron Doped DLC under Engine Oil
description DLC films are of significant interest for automobile parts, because they possess the potential to improve the friction property under oil lubricated conditions. In order to obtain further low friction, we focused on the combination of boron doped DLC (B-DLC) and the Mo-trimer as a lubricating oil additive, and the influence of the boron concentration on the friction property of the B-DLC films was evaluated by a block on ring type test. Compared to DLC films without boron, the B-DLC films exhibited an extremely low friction coefficient below 0.03 ranging from 2 to 12 at% in boron concentration under the lubricating condition using the engine oil containing the Mo-trimer. It was found that the surface roughness of the B-DLC films rubbed in the oil containing the Mo-trimer became particularly smooth below 2 nm measured by an atomic force microscope. On the wear surface of the B-DLC films, Mo3S7- derived from the Mo-trimer was selectively confirmed as having a uniform distribution by time-of-flight secondary ion mass spectrometry. Based on the obtained results of surface measurements and analyses, it was suggested that the B-DLC films exhibited a low friction property primarily caused by the nano-scale smooth surface, disturbing the adsorption of the other additives and the transfer reaction products from the counter parts by forming a selective adsorbed Mo-trimer film on the B-DLC surface.
format article
author Hiroyuki Mori
Mamoru Tohyama
Masaru Okuyama
Toshihide Ohmori
Naoya Ikeda
Keiji Hayashi
author_facet Hiroyuki Mori
Mamoru Tohyama
Masaru Okuyama
Toshihide Ohmori
Naoya Ikeda
Keiji Hayashi
author_sort Hiroyuki Mori
title Low Friction Property of Boron Doped DLC under Engine Oil
title_short Low Friction Property of Boron Doped DLC under Engine Oil
title_full Low Friction Property of Boron Doped DLC under Engine Oil
title_fullStr Low Friction Property of Boron Doped DLC under Engine Oil
title_full_unstemmed Low Friction Property of Boron Doped DLC under Engine Oil
title_sort low friction property of boron doped dlc under engine oil
publisher Japanese Society of Tribologists
publishDate 2017
url https://doaj.org/article/4cc7af21cab44a089ebd92d0ec8e1028
work_keys_str_mv AT hiroyukimori lowfrictionpropertyofborondopeddlcunderengineoil
AT mamorutohyama lowfrictionpropertyofborondopeddlcunderengineoil
AT masaruokuyama lowfrictionpropertyofborondopeddlcunderengineoil
AT toshihideohmori lowfrictionpropertyofborondopeddlcunderengineoil
AT naoyaikeda lowfrictionpropertyofborondopeddlcunderengineoil
AT keijihayashi lowfrictionpropertyofborondopeddlcunderengineoil
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