Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221

Zirconium-based metal–organic frameworks have defective structures that are useful in catalysis and gas storage. Here, the authors study the interplay between cluster disorder and linker vacancies in PCN-221 and propose a new structure model with tilted Zr6O4(OH)4 clusters rather than Zr8O6 clusters...

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Autores principales:	Charlotte Koschnick, Robert Stäglich, Tanja Scholz, Maxwell W. Terban, Alberto von Mankowski, Gökcen Savasci, Florian Binder, Alexander Schökel, Martin Etter, Jürgen Nuss, Renée Siegel, Luzia S. Germann, Christian Ochsenfeld, Robert E. Dinnebier, Jürgen Senker, Bettina V. Lotsch
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/4cd9388989264db0b0a01d8d0950154a
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spelling	oai:doaj.org-article:4cd9388989264db0b0a01d8d0950154a2021-12-02T15:00:58ZUnderstanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-22110.1038/s41467-021-23348-w2041-1723https://doaj.org/article/4cd9388989264db0b0a01d8d0950154a2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23348-whttps://doaj.org/toc/2041-1723Zirconium-based metal–organic frameworks have defective structures that are useful in catalysis and gas storage. Here, the authors study the interplay between cluster disorder and linker vacancies in PCN-221 and propose a new structure model with tilted Zr6O4(OH)4 clusters rather than Zr8O6 clusters.Charlotte KoschnickRobert StäglichTanja ScholzMaxwell W. TerbanAlberto von MankowskiGökcen SavasciFlorian BinderAlexander SchökelMartin EtterJürgen NussRenée SiegelLuzia S. GermannChristian OchsenfeldRobert E. DinnebierJürgen SenkerBettina V. LotschNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Charlotte Koschnick Robert Stäglich Tanja Scholz Maxwell W. Terban Alberto von Mankowski Gökcen Savasci Florian Binder Alexander Schökel Martin Etter Jürgen Nuss Renée Siegel Luzia S. Germann Christian Ochsenfeld Robert E. Dinnebier Jürgen Senker Bettina V. Lotsch Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221
description	Zirconium-based metal–organic frameworks have defective structures that are useful in catalysis and gas storage. Here, the authors study the interplay between cluster disorder and linker vacancies in PCN-221 and propose a new structure model with tilted Zr6O4(OH)4 clusters rather than Zr8O6 clusters.
format	article
author	Charlotte Koschnick Robert Stäglich Tanja Scholz Maxwell W. Terban Alberto von Mankowski Gökcen Savasci Florian Binder Alexander Schökel Martin Etter Jürgen Nuss Renée Siegel Luzia S. Germann Christian Ochsenfeld Robert E. Dinnebier Jürgen Senker Bettina V. Lotsch
author_facet	Charlotte Koschnick Robert Stäglich Tanja Scholz Maxwell W. Terban Alberto von Mankowski Gökcen Savasci Florian Binder Alexander Schökel Martin Etter Jürgen Nuss Renée Siegel Luzia S. Germann Christian Ochsenfeld Robert E. Dinnebier Jürgen Senker Bettina V. Lotsch
author_sort	Charlotte Koschnick
title	Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221
title_short	Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221
title_full	Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221
title_fullStr	Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221
title_full_unstemmed	Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221
title_sort	understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the zr8o6 cluster conundrum in pcn-221
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/4cd9388989264db0b0a01d8d0950154a
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Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221

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