C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property

Abstract Electrical conductive poly(phenylene sulfide) (PPS)/fullerene (C60) composites were prepared by 1-chlornaphthalene blending method, and the interface effects of C60 and PPS on PPS/C60 properties were characterized. C60 is an excellent nanofiller for PPS, and 2 wt% PPS/C60 composite displaye...

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Autores principales:	Maliang Zhang, Xiaotian Wang, Yali Bai, Zhenhuan Li, Bowen Cheng
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/4d6fe86a40d14126a8256031e51fca2b
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spelling	oai:doaj.org-article:4d6fe86a40d14126a8256031e51fca2b2021-12-02T11:40:53ZC60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property10.1038/s41598-017-04491-12045-2322https://doaj.org/article/4d6fe86a40d14126a8256031e51fca2b2017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-04491-1https://doaj.org/toc/2045-2322Abstract Electrical conductive poly(phenylene sulfide) (PPS)/fullerene (C60) composites were prepared by 1-chlornaphthalene blending method, and the interface effects of C60 and PPS on PPS/C60 properties were characterized. C60 is an excellent nanofiller for PPS, and 2 wt% PPS/C60 composite displayed the optimal conductivity which achieved 1.67 × 10−2 S/cm. However, when C60 concentration reached 2 wt%, the breaking strength and tensile modulus of PPS/C60 fiber achieved maximum 290 MPa and 605 MPa, and those values were 7.72 and 11.2 times as that of pure PPS. The excellent conductive and mechanical properties of PPS/C60 were attributed to the heterogeneous nucleation of C60 during PPS crystallization, formation of a large number of covalent bond by main C60-thiol adducts and minor C60-ArCl alkylation between C60 outer surface and PPS matrix. At same time, PPS/C60 thermal properties were also investigated.Maliang ZhangXiaotian WangYali BaiZhenhuan LiBowen ChengNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-11 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Maliang Zhang Xiaotian Wang Yali Bai Zhenhuan Li Bowen Cheng C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
description	Abstract Electrical conductive poly(phenylene sulfide) (PPS)/fullerene (C60) composites were prepared by 1-chlornaphthalene blending method, and the interface effects of C60 and PPS on PPS/C60 properties were characterized. C60 is an excellent nanofiller for PPS, and 2 wt% PPS/C60 composite displayed the optimal conductivity which achieved 1.67 × 10−2 S/cm. However, when C60 concentration reached 2 wt%, the breaking strength and tensile modulus of PPS/C60 fiber achieved maximum 290 MPa and 605 MPa, and those values were 7.72 and 11.2 times as that of pure PPS. The excellent conductive and mechanical properties of PPS/C60 were attributed to the heterogeneous nucleation of C60 during PPS crystallization, formation of a large number of covalent bond by main C60-thiol adducts and minor C60-ArCl alkylation between C60 outer surface and PPS matrix. At same time, PPS/C60 thermal properties were also investigated.
format	article
author	Maliang Zhang Xiaotian Wang Yali Bai Zhenhuan Li Bowen Cheng
author_facet	Maliang Zhang Xiaotian Wang Yali Bai Zhenhuan Li Bowen Cheng
author_sort	Maliang Zhang
title	C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
title_short	C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
title_full	C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
title_fullStr	C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
title_full_unstemmed	C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
title_sort	c60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/4d6fe86a40d14126a8256031e51fca2b
work_keys_str_mv	AT maliangzhang c60asfinefillerstoimprovepolyphenylenesulfideelectricalconductivityandmechanicalproperty AT xiaotianwang c60asfinefillerstoimprovepolyphenylenesulfideelectricalconductivityandmechanicalproperty AT yalibai c60asfinefillerstoimprovepolyphenylenesulfideelectricalconductivityandmechanicalproperty AT zhenhuanli c60asfinefillerstoimprovepolyphenylenesulfideelectricalconductivityandmechanicalproperty AT bowencheng c60asfinefillerstoimprovepolyphenylenesulfideelectricalconductivityandmechanicalproperty
_version_	1718395514501726208

C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property

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