Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission
Hybrid halide perovskites are semicondoctor materials with desirable characteristics of color-tunable and narrow-band emissions for lighting and display technology. They have size-tunable emissions due to quantum size effects. In this work, the Formamidinium Lead Bromide perovskite CH(NH2)2PbBr3 nan...
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oai:doaj.org-article:4e875ff2088146a4ab12d53c0b980fca2021-12-02T17:13:38ZSynthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission2261-236X10.1051/matecconf/202134801015https://doaj.org/article/4e875ff2088146a4ab12d53c0b980fca2021-01-01T00:00:00Zhttps://www.matec-conferences.org/articles/matecconf/pdf/2021/17/matecconf_inbes2021_01015.pdfhttps://doaj.org/toc/2261-236XHybrid halide perovskites are semicondoctor materials with desirable characteristics of color-tunable and narrow-band emissions for lighting and display technology. They have size-tunable emissions due to quantum size effects. In this work, the Formamidinium Lead Bromide perovskite CH(NH2)2PbBr3 nanoplatelets (NPLs) were successfully synthesized by ligand-assisted reprecipitation method under room condition, in which the emission color-tunability was realized via quantum size effect without anion–halide mixing, by varying the oleylamine to oleic acid volume ratio as surfactants, while the total amount of oleic acid remained unchanged. We are able to adjust the optical proprieties of FAPbBr3 NPLs and, consequently, their structural properties. The obtained colloidal solutions of FAPbBr3 nanoplatelets with uniform size exhibited different photoluminescence wavelengths covering the spectral region from 440 to 525 nm. The maximum absolute PL quantum yield (PLQY) of the green emission was measured to be as high as 80% at room temperature. The size of FAPbBr3 NPLs could be effectively tuned from 15.5 to 38.1 nm with an increase in the oleylamine and oleic acid ligands ratio.Jarmouni NabilaTomaiuolo MarcoGabbani AlessioPineider FrancescoBassam RajaaBelaaouad SaidBenmokhtar SaidEDP SciencesarticleEngineering (General). Civil engineering (General)TA1-2040ENFRMATEC Web of Conferences, Vol 348, p 01015 (2021) |
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Engineering (General). Civil engineering (General) TA1-2040 |
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Engineering (General). Civil engineering (General) TA1-2040 Jarmouni Nabila Tomaiuolo Marco Gabbani Alessio Pineider Francesco Bassam Rajaa Belaaouad Said Benmokhtar Said Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission |
description |
Hybrid halide perovskites are semicondoctor materials with desirable characteristics of color-tunable and narrow-band emissions for lighting and display technology. They have size-tunable emissions due to quantum size effects. In this work, the Formamidinium Lead Bromide perovskite CH(NH2)2PbBr3 nanoplatelets (NPLs) were successfully synthesized by ligand-assisted reprecipitation method under room condition, in which the emission color-tunability was realized via quantum size effect without anion–halide mixing, by varying the oleylamine to oleic acid volume ratio as surfactants, while the total amount of oleic acid remained unchanged. We are able to adjust the optical proprieties of FAPbBr3 NPLs and, consequently, their structural properties. The obtained colloidal solutions of FAPbBr3 nanoplatelets with uniform size exhibited different photoluminescence wavelengths covering the spectral region from 440 to 525 nm. The maximum absolute PL quantum yield (PLQY) of the green emission was measured to be as high as 80% at room temperature. The size of FAPbBr3 NPLs could be effectively tuned from 15.5 to 38.1 nm with an increase in the oleylamine and oleic acid ligands ratio. |
format |
article |
author |
Jarmouni Nabila Tomaiuolo Marco Gabbani Alessio Pineider Francesco Bassam Rajaa Belaaouad Said Benmokhtar Said |
author_facet |
Jarmouni Nabila Tomaiuolo Marco Gabbani Alessio Pineider Francesco Bassam Rajaa Belaaouad Said Benmokhtar Said |
author_sort |
Jarmouni Nabila |
title |
Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission |
title_short |
Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission |
title_full |
Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission |
title_fullStr |
Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission |
title_full_unstemmed |
Synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite FAPbBr3 nanoplatelets with tunable emission |
title_sort |
synthesis of brightly luminescent colloidal formamidinium lead bromide perovskite fapbbr3 nanoplatelets with tunable emission |
publisher |
EDP Sciences |
publishDate |
2021 |
url |
https://doaj.org/article/4e875ff2088146a4ab12d53c0b980fca |
work_keys_str_mv |
AT jarmouninabila synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission AT tomaiuolomarco synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission AT gabbanialessio synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission AT pineiderfrancesco synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission AT bassamrajaa synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission AT belaaouadsaid synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission AT benmokhtarsaid synthesisofbrightlyluminescentcolloidalformamidiniumleadbromideperovskitefapbbr3nanoplateletswithtunableemission |
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