Ni(II)-catalyzed asymmetric alkenylations of ketimines
Chiral allylic amines are often encountered in bioactive compounds and can be conveniently transformed into other chiral amines. Here, the authors report nickel-catalyzed enantioselective addition and addition/ring-expansion of alkenylboronic acids to ketimines providing a range of valuable chiral a...
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Nature Portfolio
2018
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oai:doaj.org-article:4ea6fbe9e6e64457912e14a2869e2fe12021-12-02T16:56:55ZNi(II)-catalyzed asymmetric alkenylations of ketimines10.1038/s41467-018-04645-32041-1723https://doaj.org/article/4ea6fbe9e6e64457912e14a2869e2fe12018-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04645-3https://doaj.org/toc/2041-1723Chiral allylic amines are often encountered in bioactive compounds and can be conveniently transformed into other chiral amines. Here, the authors report nickel-catalyzed enantioselective addition and addition/ring-expansion of alkenylboronic acids to ketimines providing a range of valuable chiral azaheterocycles.Mao QuanXiaoxiao WangLiang WuIlya D. GridnevGuoqiang YangWanbin ZhangNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-11 (2018) |
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Science Q Mao Quan Xiaoxiao Wang Liang Wu Ilya D. Gridnev Guoqiang Yang Wanbin Zhang Ni(II)-catalyzed asymmetric alkenylations of ketimines |
description |
Chiral allylic amines are often encountered in bioactive compounds and can be conveniently transformed into other chiral amines. Here, the authors report nickel-catalyzed enantioselective addition and addition/ring-expansion of alkenylboronic acids to ketimines providing a range of valuable chiral azaheterocycles. |
format |
article |
author |
Mao Quan Xiaoxiao Wang Liang Wu Ilya D. Gridnev Guoqiang Yang Wanbin Zhang |
author_facet |
Mao Quan Xiaoxiao Wang Liang Wu Ilya D. Gridnev Guoqiang Yang Wanbin Zhang |
author_sort |
Mao Quan |
title |
Ni(II)-catalyzed asymmetric alkenylations of ketimines |
title_short |
Ni(II)-catalyzed asymmetric alkenylations of ketimines |
title_full |
Ni(II)-catalyzed asymmetric alkenylations of ketimines |
title_fullStr |
Ni(II)-catalyzed asymmetric alkenylations of ketimines |
title_full_unstemmed |
Ni(II)-catalyzed asymmetric alkenylations of ketimines |
title_sort |
ni(ii)-catalyzed asymmetric alkenylations of ketimines |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/4ea6fbe9e6e64457912e14a2869e2fe1 |
work_keys_str_mv |
AT maoquan niiicatalyzedasymmetricalkenylationsofketimines AT xiaoxiaowang niiicatalyzedasymmetricalkenylationsofketimines AT liangwu niiicatalyzedasymmetricalkenylationsofketimines AT ilyadgridnev niiicatalyzedasymmetricalkenylationsofketimines AT guoqiangyang niiicatalyzedasymmetricalkenylationsofketimines AT wanbinzhang niiicatalyzedasymmetricalkenylationsofketimines |
_version_ |
1718382678637543424 |