Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction

Abstract A hybrid system was designed and synthesized through reacting modified halloysite (Hal-Cl) with Schiff base (DAB-PC) and applied as catalytic support for anchoring Pd NPs to afford Pd@Hal-DAB-PC catalyst. The resultant material was well identified by various analyses including Fourier trans...

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Autores principales:	Mansoureh Daraie, Majid M. Heravi, Yalda Rangraz, Zahra Besharati
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/4ebc7d12ffc043d19737216a397ba86e
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spelling	oai:doaj.org-article:4ebc7d12ffc043d19737216a397ba86e2021-12-02T11:39:43ZPd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction10.1038/s41598-021-85821-22045-2322https://doaj.org/article/4ebc7d12ffc043d19737216a397ba86e2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-85821-2https://doaj.org/toc/2045-2322Abstract A hybrid system was designed and synthesized through reacting modified halloysite (Hal-Cl) with Schiff base (DAB-PC) and applied as catalytic support for anchoring Pd NPs to afford Pd@Hal-DAB-PC catalyst. The resultant material was well identified by various analyses including Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction patterns (XRD), thermogravimetric analysis (TGA), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and inductively coupled plasma-optical emission spectrometry (ICP-OES) and revealed outstanding catalytic activity in the Sonogashira reaction in aqueous media. Also, This nanocatalyst was simply collected and recycled up to six runs with a slight drop in efficiency, indicating the durability of Pd@Hal-DAB-PC.Mansoureh DaraieMajid M. HeraviYalda RangrazZahra BesharatiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Mansoureh Daraie Majid M. Heravi Yalda Rangraz Zahra Besharati Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction
description	Abstract A hybrid system was designed and synthesized through reacting modified halloysite (Hal-Cl) with Schiff base (DAB-PC) and applied as catalytic support for anchoring Pd NPs to afford Pd@Hal-DAB-PC catalyst. The resultant material was well identified by various analyses including Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction patterns (XRD), thermogravimetric analysis (TGA), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and inductively coupled plasma-optical emission spectrometry (ICP-OES) and revealed outstanding catalytic activity in the Sonogashira reaction in aqueous media. Also, This nanocatalyst was simply collected and recycled up to six runs with a slight drop in efficiency, indicating the durability of Pd@Hal-DAB-PC.
format	article
author	Mansoureh Daraie Majid M. Heravi Yalda Rangraz Zahra Besharati
author_facet	Mansoureh Daraie Majid M. Heravi Yalda Rangraz Zahra Besharati
author_sort	Mansoureh Daraie
title	Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction
title_short	Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction
title_full	Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction
title_fullStr	Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction
title_full_unstemmed	Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction
title_sort	pd nps supported on halloysite functionalized with schiff base as an efficient catalyst for sonogashira reaction
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/4ebc7d12ffc043d19737216a397ba86e
work_keys_str_mv	AT mansourehdaraie pdnpssupportedonhalloysitefunctionalizedwithschiffbaseasanefficientcatalystforsonogashirareaction AT majidmheravi pdnpssupportedonhalloysitefunctionalizedwithschiffbaseasanefficientcatalystforsonogashirareaction AT yaldarangraz pdnpssupportedonhalloysitefunctionalizedwithschiffbaseasanefficientcatalystforsonogashirareaction AT zahrabesharati pdnpssupportedonhalloysitefunctionalizedwithschiffbaseasanefficientcatalystforsonogashirareaction
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Pd NPs supported on halloysite functionalized with Schiff base as an efficient catalyst for Sonogashira reaction

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