Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose

Transforming biomass waste into cost-effective catalysts for chemical reactions provides new opportunity for biomass waste valorization. In this work, we examined the possibility of using food waste solid digestate as raw materials for the production of a heterogeneous catalyst for glucose isomeriza...

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Autores principales:	Raffel Dharma Patria, Md Khairul Islam, Liwen Luo, Shao-Yuan Leu, Sunita Varjani, Yunjie Xu, Jonathan Woon-Chung Wong, Jun Zhao
Formato:	article
Lenguaje:	EN
Publicado:	KeAi Communications Co. Ltd. 2021
Materias:	Glucose isomerization Fructose Digestate Hydroxyapatite Catalyst Chemical technology TP1-1185 Biochemistry QD415-436
Acceso en línea:	https://doaj.org/article/4f04aadccc4e4c2ca7b6ea86d74babff
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spelling	oai:doaj.org-article:4f04aadccc4e4c2ca7b6ea86d74babff2021-12-02T05:03:56ZHydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose2666-554910.1016/j.gresc.2021.08.004https://doaj.org/article/4f04aadccc4e4c2ca7b6ea86d74babff2021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2666554921000764https://doaj.org/toc/2666-5549Transforming biomass waste into cost-effective catalysts for chemical reactions provides new opportunity for biomass waste valorization. In this work, we examined the possibility of using food waste solid digestate as raw materials for the production of a heterogeneous catalyst for glucose isomerization to fructose, which is one of the important intermediates for the production of platform chemicals, hydrocarbon fuels and synthetic materials from biomass. Hydroxyapatite-based catalysts were obtained from food waste digestate by a coupled hydrothermal-calcination approach. In the hydrothermal treatment process, the addition of exogenous calcium can adjust the alkalinity of the catalyst, which is beneficial to improve the activity of the catalyst. The reaction parameters such as reaction temperature, reaction time and catalyst dosage have also been optimized. The catalyst showed excellent catalytic performance in the glucose isomerization reaction resulting in a high fructose yield of 32.3% with a reaction time of only 20 min at 80 °C in water. The catalyst can be reused after a simple regeneration without significant activity. This work provides a win-win strategy, which not only solves the problem of the disposal and utilization of digestate, but also expands the synthesis method of the glucose isomerization reaction catalyst.Raffel Dharma PatriaMd Khairul IslamLiwen LuoShao-Yuan LeuSunita VarjaniYunjie XuJonathan Woon-Chung WongJun ZhaoKeAi Communications Co. Ltd.articleGlucose isomerizationFructoseDigestateHydroxyapatiteCatalystChemical technologyTP1-1185BiochemistryQD415-436ENGreen Synthesis and Catalysis, Vol 2, Iss 4, Pp 356-361 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Glucose isomerization Fructose Digestate Hydroxyapatite Catalyst Chemical technology TP1-1185 Biochemistry QD415-436
spellingShingle	Glucose isomerization Fructose Digestate Hydroxyapatite Catalyst Chemical technology TP1-1185 Biochemistry QD415-436 Raffel Dharma Patria Md Khairul Islam Liwen Luo Shao-Yuan Leu Sunita Varjani Yunjie Xu Jonathan Woon-Chung Wong Jun Zhao Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
description	Transforming biomass waste into cost-effective catalysts for chemical reactions provides new opportunity for biomass waste valorization. In this work, we examined the possibility of using food waste solid digestate as raw materials for the production of a heterogeneous catalyst for glucose isomerization to fructose, which is one of the important intermediates for the production of platform chemicals, hydrocarbon fuels and synthetic materials from biomass. Hydroxyapatite-based catalysts were obtained from food waste digestate by a coupled hydrothermal-calcination approach. In the hydrothermal treatment process, the addition of exogenous calcium can adjust the alkalinity of the catalyst, which is beneficial to improve the activity of the catalyst. The reaction parameters such as reaction temperature, reaction time and catalyst dosage have also been optimized. The catalyst showed excellent catalytic performance in the glucose isomerization reaction resulting in a high fructose yield of 32.3% with a reaction time of only 20 min at 80 °C in water. The catalyst can be reused after a simple regeneration without significant activity. This work provides a win-win strategy, which not only solves the problem of the disposal and utilization of digestate, but also expands the synthesis method of the glucose isomerization reaction catalyst.
format	article
author	Raffel Dharma Patria Md Khairul Islam Liwen Luo Shao-Yuan Leu Sunita Varjani Yunjie Xu Jonathan Woon-Chung Wong Jun Zhao
author_facet	Raffel Dharma Patria Md Khairul Islam Liwen Luo Shao-Yuan Leu Sunita Varjani Yunjie Xu Jonathan Woon-Chung Wong Jun Zhao
author_sort	Raffel Dharma Patria
title	Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
title_short	Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
title_full	Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
title_fullStr	Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
title_full_unstemmed	Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
title_sort	hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose
publisher	KeAi Communications Co. Ltd.
publishDate	2021
url	https://doaj.org/article/4f04aadccc4e4c2ca7b6ea86d74babff
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Hydroxyapatite-based catalysts derived from food waste digestate for efficient glucose isomerization to fructose

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