Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
Polymerizations promoted by organic catalysts can produce polymeric materials without any metallic residues contamination. Here the authors show a fluorinated alcohol based catalytic system for polypeptide synthesis from α-amino acid N-carboxyanhydride, fulfilling cocatalyst and metal free condition...
Guardado en:
Autores principales: | , , , , , |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/4ff90e3c90ae47269ae55188623ede3d |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:doaj.org-article:4ff90e3c90ae47269ae55188623ede3d |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:4ff90e3c90ae47269ae55188623ede3d2021-12-02T17:01:53ZFast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst10.1038/s41467-019-11524-y2041-1723https://doaj.org/article/4ff90e3c90ae47269ae55188623ede3d2019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11524-yhttps://doaj.org/toc/2041-1723Polymerizations promoted by organic catalysts can produce polymeric materials without any metallic residues contamination. Here the authors show a fluorinated alcohol based catalytic system for polypeptide synthesis from α-amino acid N-carboxyanhydride, fulfilling cocatalyst and metal free conditions with high rate and selectivity.Wei ZhaoYanfeng LvJi LiZihao FengYonghao NiNikos HadjichristidisNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
Science Q |
spellingShingle |
Science Q Wei Zhao Yanfeng Lv Ji Li Zihao Feng Yonghao Ni Nikos Hadjichristidis Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
description |
Polymerizations promoted by organic catalysts can produce polymeric materials without any metallic residues contamination. Here the authors show a fluorinated alcohol based catalytic system for polypeptide synthesis from α-amino acid N-carboxyanhydride, fulfilling cocatalyst and metal free conditions with high rate and selectivity. |
format |
article |
author |
Wei Zhao Yanfeng Lv Ji Li Zihao Feng Yonghao Ni Nikos Hadjichristidis |
author_facet |
Wei Zhao Yanfeng Lv Ji Li Zihao Feng Yonghao Ni Nikos Hadjichristidis |
author_sort |
Wei Zhao |
title |
Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
title_short |
Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
title_full |
Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
title_fullStr |
Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
title_full_unstemmed |
Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
title_sort |
fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/4ff90e3c90ae47269ae55188623ede3d |
work_keys_str_mv |
AT weizhao fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst AT yanfenglv fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst AT jili fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst AT zihaofeng fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst AT yonghaoni fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst AT nikoshadjichristidis fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst |
_version_ |
1718382028172296192 |