Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst

Polymerizations promoted by organic catalysts can produce polymeric materials without any metallic residues contamination. Here the authors show a fluorinated alcohol based catalytic system for polypeptide synthesis from α-amino acid N-carboxyanhydride, fulfilling cocatalyst and metal free condition...

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Autores principales: Wei Zhao, Yanfeng Lv, Ji Li, Zihao Feng, Yonghao Ni, Nikos Hadjichristidis
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/4ff90e3c90ae47269ae55188623ede3d
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spelling oai:doaj.org-article:4ff90e3c90ae47269ae55188623ede3d2021-12-02T17:01:53ZFast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst10.1038/s41467-019-11524-y2041-1723https://doaj.org/article/4ff90e3c90ae47269ae55188623ede3d2019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11524-yhttps://doaj.org/toc/2041-1723Polymerizations promoted by organic catalysts can produce polymeric materials without any metallic residues contamination. Here the authors show a fluorinated alcohol based catalytic system for polypeptide synthesis from α-amino acid N-carboxyanhydride, fulfilling cocatalyst and metal free conditions with high rate and selectivity.Wei ZhaoYanfeng LvJi LiZihao FengYonghao NiNikos HadjichristidisNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Wei Zhao
Yanfeng Lv
Ji Li
Zihao Feng
Yonghao Ni
Nikos Hadjichristidis
Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
description Polymerizations promoted by organic catalysts can produce polymeric materials without any metallic residues contamination. Here the authors show a fluorinated alcohol based catalytic system for polypeptide synthesis from α-amino acid N-carboxyanhydride, fulfilling cocatalyst and metal free conditions with high rate and selectivity.
format article
author Wei Zhao
Yanfeng Lv
Ji Li
Zihao Feng
Yonghao Ni
Nikos Hadjichristidis
author_facet Wei Zhao
Yanfeng Lv
Ji Li
Zihao Feng
Yonghao Ni
Nikos Hadjichristidis
author_sort Wei Zhao
title Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
title_short Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
title_full Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
title_fullStr Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
title_full_unstemmed Fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
title_sort fast and selective organocatalytic ring-opening polymerization by fluorinated alcohol without a cocatalyst
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/4ff90e3c90ae47269ae55188623ede3d
work_keys_str_mv AT weizhao fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst
AT yanfenglv fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst
AT jili fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst
AT zihaofeng fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst
AT yonghaoni fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst
AT nikoshadjichristidis fastandselectiveorganocatalyticringopeningpolymerizationbyfluorinatedalcoholwithoutacocatalyst
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