Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers

Mesoporous polymer networks were prepared via the cross-linking radical copolymerization of non-toxic hydrophilic <i>N</i>-vinylpyrrolidone (VP) with triethylene glycol dimethacrylate (TEGDM) and poly(ethylene glycol) methyl ester methacrylate (PEGMMA) in bulk, using appropriate soluble...

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Autores principales:	Svetlana V. Kurmaz, Natalia V. Fadeeva, Anna I. Gorshkova, Sergey A. Kurochkin, Eugenia I. Knerelman, Galina I. Davydova, Vladimir I. Torbov, Nadezhda N. Dremova, Dmitry V. Konev, Vladimir A. Kurmaz, Vladislav M. Ignatiev, Nina S. Emelyanova
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	<i>N</i>-vinylpyrrolidone (di)methacrylates porogens nanopores Rose Bengal sorption Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Acceso en línea:	https://doaj.org/article/505c2446bb334248aad096754452b58b
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spelling	oai:doaj.org-article:505c2446bb334248aad096754452b58b2021-11-25T18:13:20ZMesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers10.3390/ma142267571996-1944https://doaj.org/article/505c2446bb334248aad096754452b58b2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/6757https://doaj.org/toc/1996-1944Mesoporous polymer networks were prepared via the cross-linking radical copolymerization of non-toxic hydrophilic <i>N</i>-vinylpyrrolidone (VP) with triethylene glycol dimethacrylate (TEGDM) and poly(ethylene glycol) methyl ester methacrylate (PEGMMA) in bulk, using appropriate soluble and thermodynamically compatible macromolecular additives with a branched structure as porogens. The branched copolymers of various monomer compositions were obtained by radical copolymerization in toluene, controlled by 1-decanethiol, and these materials were characterized by a wide set of physical chemical methods. The specific surface areas and surface morphology of the polymer networks were determined by nitrogen low-temperature adsorption or Rose Bengal (RB) sorption, depending on the copolymer compositions and scanning electron microscopy. The electrochemical properties of RB before and after its encapsulation into a branched VP copolymer were studied on a glassy carbon electrode and the interaction between these substances was observed. Quantum chemical modeling of RB-VP or RB-copolymer complexes has been carried out and sufficiently strong hydrogen bonds were found in these systems. The experimental and modeling data demonstrate the high potency of such mesoporous polymer networks as precursors of molecularly imprinted polymers for the recognition of fluorescent dyes as nanomarkers for biomedical practice.Svetlana V. KurmazNatalia V. FadeevaAnna I. GorshkovaSergey A. KurochkinEugenia I. KnerelmanGalina I. DavydovaVladimir I. TorbovNadezhda N. DremovaDmitry V. KonevVladimir A. KurmazVladislav M. IgnatievNina S. EmelyanovaMDPI AGarticle<i>N</i>-vinylpyrrolidone(di)methacrylatesporogensnanoporesRose BengalsorptionTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6757, p 6757 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	<i>N</i>-vinylpyrrolidone (di)methacrylates porogens nanopores Rose Bengal sorption Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
spellingShingle	<i>N</i>-vinylpyrrolidone (di)methacrylates porogens nanopores Rose Bengal sorption Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Svetlana V. Kurmaz Natalia V. Fadeeva Anna I. Gorshkova Sergey A. Kurochkin Eugenia I. Knerelman Galina I. Davydova Vladimir I. Torbov Nadezhda N. Dremova Dmitry V. Konev Vladimir A. Kurmaz Vladislav M. Ignatiev Nina S. Emelyanova Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers
description	Mesoporous polymer networks were prepared via the cross-linking radical copolymerization of non-toxic hydrophilic <i>N</i>-vinylpyrrolidone (VP) with triethylene glycol dimethacrylate (TEGDM) and poly(ethylene glycol) methyl ester methacrylate (PEGMMA) in bulk, using appropriate soluble and thermodynamically compatible macromolecular additives with a branched structure as porogens. The branched copolymers of various monomer compositions were obtained by radical copolymerization in toluene, controlled by 1-decanethiol, and these materials were characterized by a wide set of physical chemical methods. The specific surface areas and surface morphology of the polymer networks were determined by nitrogen low-temperature adsorption or Rose Bengal (RB) sorption, depending on the copolymer compositions and scanning electron microscopy. The electrochemical properties of RB before and after its encapsulation into a branched VP copolymer were studied on a glassy carbon electrode and the interaction between these substances was observed. Quantum chemical modeling of RB-VP or RB-copolymer complexes has been carried out and sufficiently strong hydrogen bonds were found in these systems. The experimental and modeling data demonstrate the high potency of such mesoporous polymer networks as precursors of molecularly imprinted polymers for the recognition of fluorescent dyes as nanomarkers for biomedical practice.
format	article
author	Svetlana V. Kurmaz Natalia V. Fadeeva Anna I. Gorshkova Sergey A. Kurochkin Eugenia I. Knerelman Galina I. Davydova Vladimir I. Torbov Nadezhda N. Dremova Dmitry V. Konev Vladimir A. Kurmaz Vladislav M. Ignatiev Nina S. Emelyanova
author_facet	Svetlana V. Kurmaz Natalia V. Fadeeva Anna I. Gorshkova Sergey A. Kurochkin Eugenia I. Knerelman Galina I. Davydova Vladimir I. Torbov Nadezhda N. Dremova Dmitry V. Konev Vladimir A. Kurmaz Vladislav M. Ignatiev Nina S. Emelyanova
author_sort	Svetlana V. Kurmaz
title	Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers
title_short	Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers
title_full	Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers
title_fullStr	Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers
title_full_unstemmed	Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers
title_sort	mesoporous networks of <i>n</i>-vinylpyrrolidone with (di)methacrylates as precursors of ecological molecular imprinted polymers
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/505c2446bb334248aad096754452b58b
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Mesoporous Networks of <i>N</i>-Vinylpyrrolidone with (di)Methacrylates as Precursors of Ecological Molecular Imprinted Polymers

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